#9I;ANTI-(2S,3S)-1-[(2S,4R)-2-TERT.-BUTOXYMETHYL-4-METHOXY-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY
Compound with spectra: 1 NMR
![#9I;ANTI-(2S,3S)-1-[(2S,4R)-2-TERT.-BUTOXYMETHYL-4-METHOXY-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY](/api/compound/BzfIVAM02lM.png?ph=true&h=300&w=458 "#9I;ANTI-(2S,3S)-1-[(2S,4R)-2-TERT.-BUTOXYMETHYL-4-METHOXY-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY")
| SpectraBase Compound ID | BzfIVAM02lM |
|---|---|
| InChI | InChI=1S/2C44H61NO5Si/c2*1-33(2)40(25-18-28-50-51(44(6,7)8,38-21-13-11-14-22-38)39-23-15-12-16-24-39)41(27-26-34-19-17-20-36(29-34)47-9)42(46)45-31-37(48-10)30-35(45)32-49-43(3,4)5/h2*11-17,19-24,26-27,29,35,37,40-41H,1,18,25,28,30-32H2,2-10H3/b2*27-26+/t2*35-,37+,40+,41-/m00/s1 |
| InChIKey | ZSIKSSNWOSNRAV-QVQQYXBVSA-N |
| Mol Weight | 1424.1 g/mol |
| Molecular Formula | C88H122N2O10Si2 |
| Exact Mass | 1422.863801 g/mol |
| Enantiomer InChIKey | ZSIKSSNWOSNRAV-WROGWVTLSA-N |
| Copyright | Copyright © 2016-2025 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#8I;ANTI-(2R,3R)-1-[(2S,4R)-2-TERT.-BUTOXYMETHYL-4-METHOXY-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY
#11H;(2,3-SYN-2):(2S,3R)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#8H;MAJOR-(2,3-ANTI):(2R,3R)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL
#9H;MINOR-(2,3-ANTI):(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL
#10H;(2,3-SYN-1):(2R,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#8K;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-TERT.-BUTOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#9K;ANTI-(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-TERT.-BUTOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#8J;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY
#9A;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENONE-
#8A;ANTI-(2R,3R)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENONE-
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |
This compound is available in the following databases:
KnowItAll NMR Spectral Library
Author: Wiley
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