(1S,3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-ONE
Compound with spectra: 1 NMR
![(1S,3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-ONE](/api/compound/BcIBKxMxseO.png?ph=true&h=300&w=458 "(1S,3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-ONE")
| SpectraBase Compound ID | BcIBKxMxseO |
|---|---|
| InChI | InChI=1S/C18H32O2Si/c1-8-9-14-16(20-21(6,7)18(3,4)5)11-13-10-15(19)12(2)17(13)14/h8,12-14,16-17H,1,9-11H2,2-7H3/t12-,13+,14+,16-,17+/m1/s1 |
| InChIKey | CPRLTYZEMWXYTN-PYOKUCOHSA-N |
| Mol Weight | 308.5 g/mol |
| Molecular Formula | C18H32O2Si |
| Exact Mass | 308.217157 g/mol |
| Enantiomer InChIKey | CPRLTYZEMWXYTN-BBOXDSQKSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
ENDO,ENDO-7,8-DIACETOXY-EXO-2-METHYL-CIS-BICYCLO-[3.3.0]-OCTAN-3-ON
2(1H)-PENTALENONE, 5,6-BIS(ACETYLOXY)HEXAHYDRO-1-METHYL-
(.alpha.R,exo,exo)-.alpha.-Methyl-6-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]bicyclo[2.2.1]heptane-2-methanol .alpha.-(4-Methylbenzenesulfonate
(.alpha.S,exo,exo)-.alpha.-Methyl-6-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]bicyclo[2.2.1]heptane-2-methanol .alpha.-(4-Methylbenzenesulfonate
(3AS,4R,5R,6AR)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4-METHYLHEXAHYDROPENTALEN-2(1H)-ONE
5-[(3aR,4S,5R,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-4-cyano-1,3a,4,5,6,6a-hexahydro-pentalen-2-yl]-pentanoic acid methyl ester
(E)-(1RS,2SR,3RS,5SR)-7-(4ï-METHOXYCARBONYL)-BUTYL-3-TERT.-BUTYLDIMETHYLSILYLOXY-2-CYANOBICYCLO-[3.3.0]-OCT-7-ENE
(1S,4aR,8S,8aS)-8-[tert-butyl(dimethyl)silyl]oxy-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxylic acid methyl ester
(1S,3aR,6R,6aR)-1,5,5-Trimethyl-6-trimethylsilanyloxy-hexahydro-pental\en-2-one
5.alpha.,7.alpha.,16-Trihydroxy-11-oxotetranor-prostanoic acid methyl ester tert-butyldimethylsilyl ether
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |