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[RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TRIISOPROPYLSILYL)-2,5-ANHYDRO-D-MANNITOL]-BF4

Compound with spectra: 2 NMR

[RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TRIISOPROPYLSILYL)-2,5-ANHYDRO-D-MANNITOL]-BF4
SpectraBase Compound ID BDOpbvK8jtC
InChI InChI=1S/C48H70O5P2Si2.C8H8.BF4.Rh/c1-35(2)56(36(3)4,37(5)6)49-33-45-47(52-54(41-25-17-13-18-26-41)42-27-19-14-20-28-42)48(46(51-45)34-50-57(38(7)8,39(9)10)40(11)12)53-55(43-29-21-15-22-30-43)44-31-23-16-24-32-44;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h13-32,35-40,45-48H,33-34H2,1-12H3;1-2,7-8H2;;/q;;2*-1/p+2/t45-,46-,47-,48-;;;/m0.../s1
InChIKey QJYURBMBPPGJMO-JRNFSDCCSA-P
Mol Weight 1141.1 g/mol
Molecular Formula C56H80BF4O5P2RhSi2
Exact Mass 1140.410361 g/mol
Parent InChIKey QZUJHMWKHQBVOV-TYWAHPBASA-P
Enantiomer InChIKey QJYURBMBPPGJMO-LMEGFMQKSA-P

View Spectrum of [RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TRIISOPROPYLSILYL)-2,5-ANHYDRO-D-MANNITOL]-BF4

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of [RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TRIISOPROPYLSILYL)-2,5-ANHYDRO-D-MANNITOL]-BF4

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
Title Journal or Book Year
C2-Symmetric Diphosphinite Ligands Derived from Carbohydrates. The Strong Influence of Remote Stereocenters on Asymmetric Rhodium-Catalyzed Hydrogenation The Journal of Organic Chemistry 2004
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