EXO-(3R,4R)-[ETA(6)-4-METHYL-3-(DIPROPYLAMINO)-CHROMAN]-CR(CO)3
Compound with spectra: 1 NMR
![EXO-(3R,4R)-[ETA(6)-4-METHYL-3-(DIPROPYLAMINO)-CHROMAN]-CR(CO)3](/api/compound/Azcf5HBQaIy.png?ph=true&h=300&w=458 "EXO-(3R,4R)-[ETA(6)-4-METHYL-3-(DIPROPYLAMINO)-CHROMAN]-CR(CO)3")
| SpectraBase Compound ID | Azcf5HBQaIy |
|---|---|
| InChI | InChI=1S/C16H21NO.3CO.Cr/c1-4-10-17(11-5-2)15-12-18-16-9-7-6-8-14(16)13(15)3;3*1-2;/h13,15H,4-5,10-12H2,1-3H3;;;;/t13-,15+;;;;/m0..../s1 |
| InChIKey | LJJHZYIAPFADFU-XTFQXXJKSA-N |
| Mol Weight | 379.38 g/mol |
| Molecular Formula | C19H21CrNO4 |
| Exact Mass | 379.087563 g/mol |
| Enantiomer InChIKey | LJJHZYIAPFADFU-DSXCFSFJSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
Methyl 2.beta.-(2'-(m-isopropyl-phenyl)ethyl)-1.beta.,3.alpha.-dimethyl-cyclohexanecarboxylate (so name and structure in Anderson & Botto) but MS (intense fragement at m/z = 187) and RT suggest 2.alpha.-epimer instead, with Reg. No. 19556-80-0? a methyl seco-dehydro-abietate
Cobalt, bis(cyano-C)(2,7,18-triethyl-1,2,6,7,12,12,15,17-octamethyl-3,8,13,17-tetrapropyl-5(6H)-corrinonato-N21,N22,N23,N24)-, [OC-6-34-[1R-(1.alpha.,2.beta.,3.alpha.,6.alpha.,7.beta.,8.alpha.,13.alpha.,17.alpha.,18.beta.,19.beta.)]]-
Diethyl 4,4''-{[(1R,2R)-cyclohexane-1,2-diyl]dinitrilo-3,3,3',3'-tetramethyl-4,4'-[(2",3",7",8"-tetrahydro-2",2",3",3",7",7",8',8'-octamethyl-11"H-dipyrrin-1",9"-diylidene)-dinitrilo]-bis[butanoato](1-)cobalt(III)
(1aR,3S,4-R,4aS,5S,8aS,9aS)-2,3,4,4a,5,7,8a,9-Octahydro-5,8a-dihydroxy-4,4a,6-trimethyl-7-oxo-1aH-oxireno[2,3:8,8a]-naphtho[2',3'-b]furan-3-yl (E)-2-Methylbut-2-enoate (E)-2-Methylbut-2-enoate(1aR,3S,4-R,4aS,5S,8aS,9aS)-2,3,4,4a,5,7,8a,9-Octahydro-5,8a-dihydroxy-4,4a,6-trimethyl-7-oxo-1aH-oxireno[2',3':8,8a]-naphtho[2,3-b]furan-3-yl (E)-2-Methylbut-2-enoate
3H-3,10b-Ethano-1H-naphtho[1,2-c]pyran-8-carboxaldehyde, 7-(1,3-dithian-2-ylidenemethylene)-4,6,6a,7,8,9,10,10a-octahydro-3-me thoxy-4,4,8-trimethyl-, [3S-(3.alpha.,6a.alpha.,7.alpha.,10a.beta.,10b.beta.)]-
(1S,6R,,9R,11R,13R)-1,5-dimethyl-9-frmyl-5-methoxycarbonyl-11-methoxy-10-oxatricyclo[7.4.0.0**9,13]tridecane
Dispiro[piperidine-4,2'-[7,14,24,31]tetraoxapentacyclo[30.2.2.23,6.215,18.220,23]dotetraconta[3,5,15,17,20,22,32,34,35,37,39,41]dodecaen e-19',4''-piperidine], 1,1''-diacetyl-5',33'-dibromo-16',22',36',37',40',41'-hexamethyl-
13',16':18',21'-dietheno-1,1''-diethyl-3',14',20',31'-tetramethyldispiro[piperidine-4,17'-[5,12,22,29]tetraoxa[37,40,41]triazatetracyclo[31.13.1.0.(4,45).0(30,35)]heptatetraconta-1',3',13',15',18',20',30',34',35',45'-decaene-47',4''-piperidine]-38',42'-dione
Iron, di-.mu.-carbonyltetracarbonyl(.eta.5-2,4-cyclopentadien-1-yl)[.mu.-[(2,4,5-.eta.:2,4,5-.eta.)-4,5-diethyl-2,3-dihydro-1,3-dimethyl-1H-1,3- diborol-2-yl-B1,B3:B1,B3]](nickel)-, (Fe-Ni)
Chromium, [.mu.-[[2,6-bis(trifluoromethyl)phenyl]diphosphenyl-P1:P1]]pentacarbonyl[carbonyl(.eta.5-2,4-cyclopentadien-1-yl)(triphenylphosphine)iron]-, stereoisomer
| Title | Journal or Book | Year |
|---|---|---|
| Alkylation of Tricarbonylchromium-Stabilized Benzylic Anions of 3-(Dipropylamino)chroman | The Journal of Organic Chemistry | 1998 |