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REL-(1S,3R,4R,5R)-4-(2-TERT.-BUTYLDIPHENYLSILYLOXY-ETHYL)-7,7-DIMETHYL-1-VINYL-2-OXA-BICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER

Compound with spectra: 2 NMR

REL-(1S,3R,4R,5R)-4-(2-TERT.-BUTYLDIPHENYLSILYLOXY-ETHYL)-7,7-DIMETHYL-1-VINYL-2-OXA-BICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER
SpectraBase Compound ID ApLrtRltfXK
InChI InChI=1S/C28H38O3Si/c1-7-28-24(20-27(28,5)6)23(25(29)31-28)18-19-30-32(26(2,3)4,21-14-10-8-11-15-21)22-16-12-9-13-17-22/h7-17,23-25,29H,1,18-20H2,2-6H3/t23-,24-,25-,28+/m0/s1
InChIKey KADLPAPZWLNITF-HQQJGFCBSA-N
Mol Weight 450.7 g/mol
Molecular Formula C28H38O3Si
Exact Mass 450.259022 g/mol
Enantiomer InChIKey KADLPAPZWLNITF-NXNJFABFSA-N

View Spectrum of REL-(1S,3R,4R,5R)-4-(2-TERT.-BUTYLDIPHENYLSILYLOXY-ETHYL)-7,7-DIMETHYL-1-VINYL-2-OXA-BICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of REL-(1S,3R,4R,5R)-4-(2-TERT.-BUTYLDIPHENYLSILYLOXY-ETHYL)-7,7-DIMETHYL-1-VINYL-2-OXA-BICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • REL-(1S,3R,4R,5R)-4-(2-TERT.-BUTYLDIPHENYLSILYLOXY-ETHYL)-7,7-DIMETHYL-1-VINYL-2-OXA-BICYCLO-[3.2.0]-HEPTAN-3-OL;MINOR-ISOMER
[3aR-(3a.alpha.,4.alpha.,7.alpha.,7a.alpha.)]-tetrahydro-N,N,2,2-tetramethyl-4-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]-4H-1,3-dioxolo[4,5-c]pyran-7-acetamide
[3aS-(3a.alpha.,4.alpha.,7a.alpha.,7.alpha.)]-1-[tetrahydro-2,2-dimethyl-4-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]-1,3-dioxolo[4,5-c]pyran-7-yl]-3-pentyn-2-one
4H-1,3-Dioxolo[4,5-c]pyran-7-ethanol, 4-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]tetrahydro-2,2-dimethyl-.alpha.-1-propynyl-, [3aS-[3a.alpha.,4.alpha.,7.alpha.(S*),7a.alpha.]]-
[3aS-[3a.alpha.,4.alpha.,7a.alpha.,7.alpha.(3E,2S*)]]-tetrahydro-2,2-dimethyl-4-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]-.alpha.-(1-propenyl)-4H-1,3-dioxolo[4,5-c]pyran-7-ethanol
(1S,4S,5S)-4-(1-((Benzoyloxymethyl)-3-((tert-butyldiphenylsilyl)oxy)propyl)-1-methyl-6-methylenebicyclo[3.3.0]oct-2-ene
(2R,3S,6S)-1-tert-Butyldiphenylsilyloxy-6-[(2R,5R,6S)-5-ethyl-5-methoxymethoxy-6-methyltetrahydropyran-2-yl]-3,6-dimethoxymethoxyheptan-2-ol
10,11-cis-[3aS-[3a.alpha.,4.alpha.,7a.alpha.,7.alpha.(2E,4S*,5R*)]]-tetrahydro-2,2-dimethyl-4-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]-7-[5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-methyl-2-hexenyl]-4H-1,3-dioxolo[4,5-c]pyran
[3aS-[3a.alpha.,4.alpha.,7a.alpha.,7.alpha.(2E,4S*,5R*)]]-tetrahydro-2,2-dimethyl-4-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]-7-[5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-methyl-2-hexenyl]-4H-1,3-dioxolo[4,5-c]pyran
(1S,3S,4S,6S)-1-[1-(2-besylethyl)vinyl]-6-[[tert-butyl(diphenyl)silyl]oxymethyl]-4-methyl-cyclohexane-1,3-diol
[.eta(4)., 7E, 9E]-Tricarbonyl-{Methyl 5,6-dihydroxy-11-[(1',1'-dimethylethyl)diphenylsilyloxy]-deca-7,9-diene-1-carboxylate}iron
Title Journal or Book Year
Samarium(II)-Mediated 4-exo-trig Cyclization. A Stereocontrolled Approach to the Core of Pestalotiopsin A Organic Letters 2001
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