(E)-(1ï-RS,1RS,5SR,7RS,8SR)-3-(1ï-DIMETHYLPHENYLSILYL-4ï-METHOXYCARBONYL)-BUTYL-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCT-2-ENE
Compound with spectra: 1 NMR
![(E)-(1ï-RS,1RS,5SR,7RS,8SR)-3-(1ï-DIMETHYLPHENYLSILYL-4ï-METHOXYCARBONYL)-BUTYL-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCT-2-ENE](/api/compound/AVAZhompTCz.png?ph=true&h=300&w=458 "(E)-(1ï-RS,1RS,5SR,7RS,8SR)-3-(1ï-DIMETHYLPHENYLSILYL-4ï-METHOXYCARBONYL)-BUTYL-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCT-2-ENE")
| SpectraBase Compound ID | AVAZhompTCz |
|---|---|
| InChI | InChI=1S/C29H45NO3Si2/c1-29(2,3)35(7,8)33-26-19-21-17-22(18-24(21)25(26)20-30)27(15-12-16-28(31)32-4)34(5,6)23-13-10-9-11-14-23/h9-11,13-14,18,21,24-27H,12,15-17,19H2,1-8H3/t21-,24-,25+,26+,27?/m0/s1 |
| InChIKey | KXYZBJZFZXIABG-MAJHSZFWSA-N |
| Mol Weight | 511.9 g/mol |
| Molecular Formula | C29H45NO3Si2 |
| Exact Mass | 511.293797 g/mol |
| Enantiomer InChIKey | KXYZBJZFZXIABG-VOATUKOZSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(E)-(1'SR,1RS,5SR,7RS,8SR)-3-(1'-Dimethylphenylsilyl-4'-methoxycarbonyl)butyl-7-tert-Butyldimethylsilyloxy-8-cyanobicyclo[3.3.0]oct-2-ene
5-[(1R,5R,6S)-1-Acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-6-cyano-hexahydro-pentalen-(2E)-ylidene]-pentanoic acid methyl ester
5-[(1S,3aS,5R,6S,6aS)-1-Acetoxy-5-(tert-butyl-dimethyl-silanyloxy)-6-cyano-hexahydro-pentalen-(2Z)-ylidene]-pentanoic acid methyl ester
(-)-(7R)-5,6-Dimethyl-7-[[(1,1-dimethylethyl)dimethylsilyl]oxy]tricyclo[4.4.0.0(5,9)]dec-3-ene
(2S,4R,5S,6R,8R,9S)-9-Benzyloxy-8-tert-butyldimethylsilyloxy-4,6-dimethyl-2-[(4S,5S)-2,2-dimethyl-5-ethyl-1,.3-dioxa-4-yl]-8-ethyl-5-(4-methoxybenzyloxy)undecan-4-ol
5-A-H,11-A-H-ELEM-3-EN-12,8-B-OLIDE,6-A-HYDROXY-14-(2'-HYDROXYISOVALEROYLOXY)
(+)-4-((1S,4S,4aS,8aR)-4-((tert-Butyl(dimethyl)silyl)oxy)-5,5,8a-trimethyl-2-methylenedecahydro-1-naphthalenyl)-2-butanone
(E,2R,3S,4S,5R,6S,7R,10S,11S)-2,7-bis[[tert-butyl(dimethyl)silyl]oxy]-3-methoxy-11-[(4-methoxyphenyl)methoxy]-4,6,8,10-tetramethyl-5-triethylsilyloxy-8-dodecenoic acid methyl ester
(1S,4aR,5S,8aR)-trimethylsilyl 1,4a-dimethyl-5-((S)-3-methyl-5-oxopentyl)-6-methylenedecahydronaphthalene-1-carboxylate
| Title | Journal or Book | Year |
|---|---|---|
| Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of a (±)-carbacyclin analogue with the geometry of the exocyclic double bond controlled by the protodesilylation of an allylsilane | Journal of the Chemical Society, Perkin Transactions 1 | 1998 |