For citations & permissions, please see: Citations & Permissions - Wiley Science Solutions*

*Links on SpectraBase are not permalinks.

ENDO-TRANS-[ETA(6)-4-BENZYL-3-(DIPROPYLAMINO)-CHROMAN]-CR(CO)3

Compound with spectra: 2 NMR

ENDO-TRANS-[ETA(6)-4-BENZYL-3-(DIPROPYLAMINO)-CHROMAN]-CR(CO)3
SpectraBase Compound ID 9Ocw1b9giqt
InChI InChI=1S/C22H25NO.3CO.Cr/c1-3-14-23(15-4-2)21-17-24-22-13-9-8-12-19(22)20(21)16-18-10-6-5-7-11-18;3*1-2;/h5-7,10-11,20-21H,3-4,14-17H2,1-2H3;;;;/t20-,21-;;;;/m1..../s1
InChIKey NAHGFNVAPFYVMD-ZPVXIRCVSA-N
Mol Weight 455.47 g/mol
Molecular Formula C25H25CrNO4
Exact Mass 455.118863 g/mol
Enantiomer InChIKey NAHGFNVAPFYVMD-GOPWMECQSA-N

View Spectrum of ENDO-TRANS-[ETA(6)-4-BENZYL-3-(DIPROPYLAMINO)-CHROMAN]-CR(CO)3

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of ENDO-TRANS-[ETA(6)-4-BENZYL-3-(DIPROPYLAMINO)-CHROMAN]-CR(CO)3

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • EXO-TRANS-4-BENZYL-[ETA(6)-3-(DIPROPYLAMINO)-CHROMAN]-CR(CO)3
[Pentamethylcyclopentadienylchronium{.mu.-.eta.(5)chronium:.eta.(3)ironcyclooctatetraene}dicanbonylirontriphenylphosphinate] complex
[(1aS,1bS,2S,5aR,6S,6aS)-1b,5a,6,6a-Tetrahydro-6-hydroxy-2-[(2-O-methyl-beta-D-glucopyranosyl)oxy]oxireno[4,5]cyclopenta[1,2-c]pyran-1a(2H)-yl]methyl 3,4-Dimethoxybenzoate
{(4a,5,6,7,7a-.eta.)-4-(2",2"-Dimethyl-1",3"-dioxolan-4"-yl)-3a,5,8,8a-tetrahydro-2,2-dimethyl-4H-indeno[5,6-d]-1,3-dioxol-5-yl}-{(4',5',6',7',7a'-.eta.)-5'-(chloromercurio)-4'-(2"',2"'-dimethyl-1'",3'"-dioxolan-4"'-yl}-3a',5',8',8a'-tetrahydro-2',2'-dimethyl-4H-indeno5,6-d]-1',3'-dioxol-5'-yl}- iron (II)
13',16':18',21'-dietheno-1,1''-diethyl-3',14',20',31'-tetramethyldispiro[piperidine-4,17'-[5,12,22,29]tetraoxa[37,40,41]triazatetracyclo[31.13.1.0.(4,45).0(30,35)]heptatetraconta-1',3',13',15',18',20',30',34',35',45'-decaene-47',4''-piperidine]-38',42'-dione
Methyl 2.beta.-(2'-(m-isopropyl-phenyl)ethyl)-1.beta.,3.alpha.-dimethyl-cyclohexanecarboxylate (so name and structure in Anderson & Botto) but MS (intense fragement at m/z = 187) and RT suggest 2.alpha.-epimer instead, with Reg. No. 19556-80-0? a methyl seco-dehydro-abietate
Butanoic Acid rel-(1R,3S,5S,6aR,7S,8S,10R,10aS)-1-(Acetyloxy)-3,5,6,6a,7,8,9,10-octahydro-5-hydroxy-7,8-dimethyl-7-(3-methylenepent-4-enyl)-1H-naphtho[1,8a -c]furan-3,10-diyl Ester
[Cyclopentadienylchronium{.mu.-.eta.(5)chronium:.eta.(3)ironcyclooctatetraene}dicanbonylirontriphenylphosphinate] complex
2-Propenoic acid, 3-phenyl-, 1,1a,1b,1c,2a,3,3a,4,6a,6b,7,8-dodecahydro-3a,6b-dihydroxy-1,1,5,7-tetramethyl-4-oxo-2a-[[(1-oxo-3-phenyl-2-propenyl)oxy]methyl]-8aH-cyclopropa[5',6']benz[1',2':7,8]az uleno[5,6-b]oxirene-8,8a-diyl ester, [1aR-(1a.alpha.,1b.beta.,1c.beta.,2a.beta.,3a.beta.,6a.alpha.,6b.alpha.,7.alpha.,8.beta.,8a.alpha.)]-
(1R*,3R*,5R*,7R*,8S*,9R*,10S*,11R*,12R*)-3-Ethoxy-6,6-dimethoxy-11-methyl-10-(t-butyldimethylsilyl)oxy-2-oxatetracyclo[7.1.0(2,8).0(3,5)]dodecan-12-ol
Dispiro[piperidine-4,2'-[7,14,24,31]tetraoxapentacyclo[30.2.2.23,6.215,18.220,23]dotetraconta[3,5,15,17,20,22,32,34,35,37,39,41]dodecaen e-19',4''-piperidine], 1,1''-diacetyl-5',33'-dibromo-16',22',36',37',40',41'-hexamethyl-
Title Journal or Book Year
Alkylation of Tricarbonylchromium-Stabilized Benzylic Anions of 3-(Dipropylamino)chroman The Journal of Organic Chemistry 1998
Other Resources
Unknown Identification

Search your unknown spectrum against the world's largest collection of reference spectra

KnowItAll Campus Solutions

KnowItAll offers faculty and students at your school access to all the tools you need for spectral analysis and structure drawing & publishing! Plus, access the world's largest spectral library.