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(1R,5R,7R)-5-(Hydroxymethyl)-8(E)-(iodomethylene)-7-methoxy-6-oxa-cis-bicyclo[3.3.0]oct-3-en-2-one

Compound with spectra: 1 NMR, and 1 MS (GC)

(1R,5R,7R)-5-(Hydroxymethyl)-8(E)-(iodomethylene)-7-methoxy-6-oxa-cis-bicyclo[3.3.0]oct-3-en-2-one
SpectraBase Compound ID 9Jv0K0YgAL6
InChI InChI=1S/C10H11IO4/c1-14-9-6(4-11)8-7(13)2-3-10(8,5-12)15-9/h2-4,8-9,12H,5H2,1H3/b6-4-/t8-,9+,10-/m0/s1
InChIKey WHXQIHMSFNHAOE-MSWXNHAGSA-N
Mol Weight 322.1 g/mol
Molecular Formula C10H11IO4
Exact Mass 321.970204 g/mol
Enantiomer InChIKey WHXQIHMSFNHAOE-VRXSJEKHSA-N

View Spectrum of (1R,5R,7R)-5-(Hydroxymethyl)-8(E)-(iodomethylene)-7-methoxy-6-oxa-cis-bicyclo[3.3.0]oct-3-en-2-one

MS (GC) Spectrum
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Source of Spectrum C-112-3504-41

View Spectrum of (1R,5R,7R)-5-(Hydroxymethyl)-8(E)-(iodomethylene)-7-methoxy-6-oxa-cis-bicyclo[3.3.0]oct-3-en-2-one

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(3aS*,6aS*,E)-3-allylidene-6a-(hydroxymethyl)-3,3a-dihydro-2H-cyclopenta[b]furan-2,4(6aH)-dione
(4S,5R)-4-hydroxy-4-[(4-methoxyphenoxy)methyl]-5-[(1E)-1-(trityloxymethyl)buta-1,3-dienyl]cyclopent-2-en-1-one
Didemnenone glycoside [8-Allylidene-5-hydroxymethyl-7-methoxybicyclo[3.3.0]oct-3-en-2-one]
JUNIPEIONOLOSIDE;3-OXO-ALPHA-IONOL-11-O-BETA-D-GLUCOPYRANOSIDE
(1R,2R,7AS)-1-ETHENYL-2-(2-BROMOPHENOXY)-PYRROLIZIDIN-3-ONE
Spiro[bicyclo[2.2.1]hept-5-ene-2,4'-[1,3]dioxolan]-5'-one, 2'-(1,1-dimethylethyl)-, [1R-[1.alpha.,2.beta.(S*),4.alpha.]]-
4-Methyl-7-A-D-glucosyl-coumarin
3H-3a,6-Epoxybenzo[c]thiophene, 6-[[(2-bromophenyl)methoxy]methyl]-1,6,7,7a-tetrahydro-, (3a.alpha.,6.alpha.,7a.beta.)-
2,2,4,7,7-Pentamethyl-3a,5a,8a,8b-tetrahydrobenzo[1,2-d ; 3,4-d']-bis[(1,3)-dioxole]
Methyl 4,6-O-benzylidene-2,3-dideoxy-3,2-C-[(2'S)-3'-hydroxybutan-1'-yl-4'-ylidene]-3-C-methyl-.alpha.-D-arabino-hexopyranoside
Title Journal or Book Year
Total syntheses of (+)- and (-)-didemnenones A and B. Anti selectivity in the intramolecular carbomercuration reaction Journal of the American Chemical Society 1990
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