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CIS,TRANS-[DIHYDRIDOBIS-(TRIPHENYLPHOSPHINE)-[N,C-2-(DIMETHYLAMINO)-PYRIDINE-1'-YLIDENE]-IRIDIUM-(III)]-FLUOROBORATE

Compound with spectra: 2 NMR

CIS,TRANS-[DIHYDRIDOBIS-(TRIPHENYLPHOSPHINE)-[N,C-2-(DIMETHYLAMINO)-PYRIDINE-1'-YLIDENE]-IRIDIUM-(III)]-FLUOROBORATE
SpectraBase Compound ID 8YTiNgXhP4
InChI InChI=1S/2C18H15P.C7H8N2.BF4.Ir.2H/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-9(2)7-5-3-4-6-8-7;2-1(3,4)5;;;/h2*1-15H;1,3-6H,2H3;;;;/q;;;2*-1;;/p+2
InChIKey QWUSCZVQWIOBTA-UHFFFAOYSA-P
Mol Weight 927.8 g/mol
Molecular Formula C43H42BF4IrN2P2
Exact Mass 928.248165 g/mol
Parent InChIKey QNTSGLBYMKRNHX-UHFFFAOYSA-P

View Spectrum of CIS,TRANS-[DIHYDRIDOBIS-(TRIPHENYLPHOSPHINE)-[N,C-2-(DIMETHYLAMINO)-PYRIDINE-1'-YLIDENE]-IRIDIUM-(III)]-FLUOROBORATE

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CD2Cl2

View Spectrum of CIS,TRANS-[DIHYDRIDOBIS-(TRIPHENYLPHOSPHINE)-[N,C-2-(DIMETHYLAMINO)-PYRIDINE-1'-YLIDENE]-IRIDIUM-(III)]-FLUOROBORATE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CD2Cl2
Methyl9-formyl-3-methyl-6-(4-methylphenyl)-1,2,3,6-tetra-hydropyrrolo[1,2-d][1,4]diazocine-5-carboxylate
IR-H-(CL)[KAPA(2)-(C,O)-C(ME)=CHC(ME)=O]-(PPH3)2
(3aR,4R,7S,7aS)-2-(naphthalen-2-yl)-3a,4,7,7a-tetrahydro-1H-spiro[4,7-methanoisoindole-8,1'-cyclopropane]-1,3(2H)-dione
2'-[2-(ETHOXYCARBONYL)-1-OXO-2-(TRIPHENYLPHOSPHORANYLIDENE)-ETHYL]-1,1'-BIPHENYL-2-CARBOXYLIC-ACID
5-anilino-1-(trideuteriomethyl)-2,1-benzoxazole-3,4,7-trione
Methyl 5-isopropyl-2-methoxy-3-nitroazulene-1-carboxylate
(5R,8S,10S,11R)-5,8-Dihydro-10,11-dihydroxy-2-phenyl-5,8-ethano-1H-[1,2,4]-triazolo[1,2-a]pyridazine-1,3(2H)-dione
N,3,3-Triphenyl-4-methyl-4-(2-methylpropenyl)-2-azetidinone
[CIS-PT(PET3)2(L4)2]2
7-Amino-2-(1H-indol-3-yl)pyrazolo[1,5-a]pyrimidine-6-carbonitrile
Title Journal or Book Year
Double Geminal C−H Activation and Reversible α-Elimination in 2-Aminopyridine Iridium(III) Complexes:  The Role of Hydrides and Solvent in Flattening the Free Energy Surface Journal of the American Chemical Society 2004
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