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TRANS-(ACETYLACETONATO)-BIS-(TRIMETHYLPHOSPHINE)-(1,5-ETA-1,2,4-TRIPHENYL-1,3-PENTADIENEDIYL)-IRIDIUM(III)

Compound with spectra: 4 NMR

TRANS-(ACETYLACETONATO)-BIS-(TRIMETHYLPHOSPHINE)-(1,5-ETA-1,2,4-TRIPHENYL-1,3-PENTADIENEDIYL)-IRIDIUM(III)
SpectraBase Compound ID 8AmTpaFfBP0
InChI InChI=1S/C23H18.C5H8O2.2C3H9P.Ir/c1-19(21-13-7-3-8-14-21)17-23(22-15-9-4-10-16-22)18-20-11-5-2-6-12-20;1-4(6)3-5(2)7;2*1-4(2)3;/h2-17H,1H2;6-7H,1-2H3;2*1-3H3;/b19-17+,23-18?;;;;
InChIKey GPTLNQAEOCVYPA-GYYBOLAUSA-N
Mol Weight 738.9 g/mol
Molecular Formula C34H44IrO2P2
Exact Mass 739.244579 g/mol

View Spectrum of TRANS-(ACETYLACETONATO)-BIS-(TRIMETHYLPHOSPHINE)-(1,5-ETA-1,2,4-TRIPHENYL-1,3-PENTADIENEDIYL)-IRIDIUM(III)

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of TRANS-(ACETYLACETONATO)-BIS-(TRIMETHYLPHOSPHINE)-(1,5-ETA-1,2,4-TRIPHENYL-1,3-PENTADIENEDIYL)-IRIDIUM(III)

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent C6D6

View Spectrum of TRANS-(ACETYLACETONATO)-BIS-(TRIMETHYLPHOSPHINE)-(1,5-ETA-1,2,4-TRIPHENYL-1,3-PENTADIENEDIYL)-IRIDIUM(III)

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent C6D6

View Spectrum of TRANS-(ACETYLACETONATO)-BIS-(TRIMETHYLPHOSPHINE)-(1,5-ETA-1,2,4-TRIPHENYL-1,3-PENTADIENEDIYL)-IRIDIUM(III)

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent C6D6
  • TRANS-ACETYLACETONATO-(1,5-ETA-1,2,4-TRIPHENYL-1,3-[1,3-(13)C(2)]-PENTADIENEDIYL)-BIS-(TRIMETHYLPHOSPHINE)-IRIDIUM(III)
  • TRANS-ACETYLACETONATO-(1,5-ETA-1,2,4-TRIPHENYL-1,3-[3,5-(13)C(2)]-PENTADIENEDIYL)-BIS-(TRIMETHYLPHOSPHINE)-IRIDIUM(III)
  • CIS-ACETYLACETONATO-(1,5-ETA-1,2,4-TRIPHENYL-1,3-[3,5-(13)C(2)]-PENTADIENEDIYL)-BIS-(TRIMETHYLPHOSPHINE)-IRIDIUM(III)
Title Journal or Book Year
Iridium-Promoted Reactions of Carbon−Carbon Bonds. Skeletal Rearrangement of a Vinylcyclopropene during Iridacyclohexadiene Formation and Subsequent Isomerization of Iridacyclohexadienes via α,α‘-Substituent Migrations Journal of the American Chemical Society 2000

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