For citations & permissions, please see: Citations & Permissions - Wiley Science Solutions*

*Links on SpectraBase are not permalinks.

(E)-(1SR,2SR,5SR,7RS,8SR)-2-DIMETHYLPHENYLSILYL-3-(4ï-METHOXYCARBONYLBUTYLIDENE)-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCTAN2

Compound with spectra: 1 NMR, and 1 MS (GC)

(E)-(1SR,2SR,5SR,7RS,8SR)-2-DIMETHYLPHENYLSILYL-3-(4ï-METHOXYCARBONYLBUTYLIDENE)-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCTAN2
SpectraBase Compound ID 86uVZw1ylrT
InChI InChI=1S/C29H45NO3Si2/c1-29(2,3)35(7,8)33-25-19-22-18-21(14-12-13-17-26(31)32-4)28(27(22)24(25)20-30)34(5,6)23-15-10-9-11-16-23/h9-11,14-16,22,24-25,27-28H,12-13,17-19H2,1-8H3/b21-14+/t22-,24-,25+,27-,28+/m0/s1
InChIKey HWBJUFNBJDFOGR-DDOMVHAPSA-N
Mol Weight 511.9 g/mol
Molecular Formula C29H45NO3Si2
Exact Mass 511.293797 g/mol
Enantiomer InChIKey HWBJUFNBJDFOGR-OKHLPIBSSA-N

View Spectrum of (E)-(1SR,2SR,5SR,7RS,8SR)-2-DIMETHYLPHENYLSILYL-3-(4ï-METHOXYCARBONYLBUTYLIDENE)-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCTAN2

MS (GC) Spectrum
Copyright Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved.
Source of Spectrum KC-0-2677-18

View Spectrum of (E)-(1SR,2SR,5SR,7RS,8SR)-2-DIMETHYLPHENYLSILYL-3-(4ï-METHOXYCARBONYLBUTYLIDENE)-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCTAN2

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • 5-[(1S,3aS,5R,6S,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-6-cyano-1-(dimethyl-phenyl-silanyl)-hexahydro-pentalen-(2E)-ylidene]-pentanoic acid methyl ester
2-Benzyl-4-(4-chlorophenyl)-N-cyclohexyl-2,3-dihydro-1H-2-benzazepin- 1-one-3-carboxamide
3-{[(t-Butyl)dimethylsilyl]oxy}-pregna-5,17(20)-dien-21-ol
2-Benzyl-N-(tert-butyl)-4-(4-nitrophenyl)-2,3-dihydro-1H-2-benzazepin- 1-one-3-carboxamide
DIOSFEBOSIDE_B
BACILOSARCIN-C
2-(4-acetylphenyl)-8a-methyl-3-phenylindolizin-1(8aH)-one
3,3,4,4-Tetracyano-5,6-diphenyl-2-(phenylimino)-3,4-dihydropyridine
Androst-5-en-17-one, 3-[(dimethylphosphinyl)oxy]-, (3.beta.)-
Dehydroisoandrosterone 3-sulfate sodium salt dihydrate
(1R)-6-Methoxy-2-{(1R)-2-methyl-3-[(triethylsilyl)oxy]-2-cyclopenten-1-yl}-1-vinyl-1,2,3,4-dihydro-1-naphthalenol
Title Journal or Book Year
Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of a (±)-carbacyclin analogue with the geometry of the exocyclic double bond controlled by the protodesilylation of an allylsilane Journal of the Chemical Society, Perkin Transactions 1 1998
Other Resources
Unknown Identification

Search your unknown spectrum against the world's largest collection of reference spectra

KnowItAll Campus Solutions

KnowItAll offers faculty and students at your school access to all the tools you need for spectral analysis and structure drawing & publishing! Plus, access the world's largest spectral library.