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(2S,3R,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-METHOXY-1,2-OXAPHOSPHINANE-2-OXIDE

Compound with spectra: 2 NMR

(2S,3R,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-METHOXY-1,2-OXAPHOSPHINANE-2-OXIDE
SpectraBase Compound ID 812VcNHVnQt
InChI InChI=1S/C33H45O7PSi/c1-33(2,3)42(5,6)40-32-31(38-24-28-20-14-9-15-21-28)30(37-23-27-18-12-8-13-19-27)29(39-41(32,34)35-4)25-36-22-26-16-10-7-11-17-26/h7-21,29-32H,22-25H2,1-6H3/t29-,30-,31+,32-,41?/m1/s1
InChIKey BMLNJERBSQWREH-OTACKQSNSA-N
Mol Weight 612.8 g/mol
Molecular Formula C33H45O7PSi
Exact Mass 612.267217 g/mol
Enantiomer InChIKey BMLNJERBSQWREH-FZKKVPCASA-N

View Spectrum of (2S,3R,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-METHOXY-1,2-OXAPHOSPHINANE-2-OXIDE

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (2S,3R,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-METHOXY-1,2-OXAPHOSPHINANE-2-OXIDE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(2S,3R,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-2-METHOXY-2-OXIDO-1,2-OXAPHOSPHINAN-3-YL-BENZOATE
(2S,3S,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-2-METHOXY-2-SULFIDO-1,2-OXAPHOSPHINAN-3-YL-METHYL-MALONATE
(2S,3S,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-2-METHOXY-2-SULFIDO-1,2-OXAPHOSPHINAN-3-YL-3-METHYLBUTANOATE
(2S,3S,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-2-METHOXY-2-SULFIDO-1,2-OXAPHOSPHINAN-3-YL-TERT.-BUTYLCARBAMATE
(2R,3S,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-2-METHOXY-2-SULFIDO-1,2-OXAPHOSPHINAN-3-YL-PIVALATE
O-[(2S,3S,4S,5S,6R)-4,5-BIS-(BENZYLOXY)-6-[(BENZYLOXY)-METHYL]-2-METHOXY-2-SULFIDO-1,2-OXAPHOSPHINAN-3-YL]-S-METHYL-CARBONODITHIOATE
5,5-DIMETHYL-2-OXO-(2',3',4',6'-TETRA-O-BENZYL-ALPHA-DGALACTOPYRANOSYL)-1,3,2-LAMBDA(5)-DIOXAPHOSPHORINAN
5,5-DIMETHYL-2-OXO-(2',3',4',6'-TETRA-O-BENZYL-BETA-D-GALACTOPYRANOSYL)-1,3,2-LAMBDA(5)-DIOXAPHOSPHORINAN
(2,3-DI-O-BENZYL-4,6-O-BENZYLIDENE-D-MANNOPYRANOSYLIDENE)-AMINO-2,4,6-TRIMETHYLBENZENE-1-SULFONATE
O-(2,3,4,6-TETRA-O-BENZYL-ALPHA-D-MANNOPYRANOSYL)-O-PIVALOYL(PIVALOYL)PHOSPHONATE
Title Journal or Book Year
Thiophostone-Derived Brønsted Acids in the Organocatalyzed Transfer Hydrogenation of Quinolines: Influence of the P-Stereogenicity European Journal of Organic Chemistry 2013
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