[[(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL]-DI-(R)-ETHYLIDENE]-BIS-[DI-(3,5-DIMETHYLPHENYL)-PHOSPHINE]
Compound with spectra: 1 NMR
![[[(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL]-DI-(R)-ETHYLIDENE]-BIS-[DI-(3,5-DIMETHYLPHENYL)-PHOSPHINE]](/api/compound/7U4vfmqa1jt.png?ph=true&h=300&w=458 "[[(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL]-DI-(R)-ETHYLIDENE]-BIS-[DI-(3,5-DIMETHYLPHENYL)-PHOSPHINE]")
| SpectraBase Compound ID | 7U4vfmqa1jt |
|---|---|
| InChI | InChI=1S/C41H52O2P2/c1-25-13-26(2)18-35(17-25)44(36-19-27(3)14-28(4)20-36)33(9)39-40(43-41(11,12)42-39)34(10)45(37-21-29(5)15-30(6)22-37)38-23-31(7)16-32(8)24-38/h13-24,33-34,39-40H,1-12H3/t33-,34-,39-,40-/m1/s1 |
| InChIKey | LPSOOLCZINBPEV-RPMZFOOHSA-N |
| Mol Weight | 638.8 g/mol |
| Molecular Formula | C41H52O2P2 |
| Exact Mass | 638.344255 g/mol |
| Enantiomer InChIKey | LPSOOLCZINBPEV-XFEDHCIASA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
1,2-BIS-[(2-S,3-S,4-S,5-S)-3,4-BIS-(BENZYLOXY)-2,5-DIMETHYLPHOSPHOLANYL]-BENZENE
(4R*,5S*,6R*)-8-BENZYLOXY-6-DIPHENYLPHOSPHINOYLOCTANE-1,4,5-TRIOL
1,3-Dioxolane-2-propanol, .beta.-(diphenylphosphinyl)-.alpha.,2-diethyl-
(4RS,5SR,6SR)-(E,E)-5-DIPHENYLPHOSPHONYL-NONA-2,7-DIENE-4,6-DIYL-DIACETATE;anti-anti-ISOMER
(4RS,6RS)-(E,E)-5-DIPHENYLPHOSPHONYL-NONA-2,7-DIENE-4,6-DIYL-DIACETATE;anti-SYN-ISOMER
(4RS,5RS).(E)-4-DIPHENYLPHOSPHINOYL-HEPT-2-ENE-1,5-DIYL-DIACETATE;SYN-ISOMER
(4RS,5SR)-(4RS,5RS)-(E)-4-Diphenylphosphinoylhept-2-ene-1,5-diyl diacetate
(4RS,5SR)-(E)-4-DIPHENYLPHOSPHINOYL-HEPT-2-ENE-1,5-DIYL-DIACETATE;anti-ISOMER
TRANS-2-(DIPHENYLPHOSPHINOYL)-CYCLOHEXYL-MESYLATE
CIS-2-(DIPHENYLPHOSPHINOYL)-CYCLOHEXYL-MESYLATE
| Title | Journal or Book | Year |
|---|---|---|
| Ligand Substituent Effects on Asymmetric Induction. Effect of Structural Variations of the DIOP Ligand on the Rh-Catalyzed Asymmetric Hydrogenation of Enamides | Organic Letters | 2000 |