(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-ISOPROPYL-4-PHENYL-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE
Compound with spectra: 1 NMR
![(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-ISOPROPYL-4-PHENYL-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE](/api/compound/6tIZnrbdAdc.png?ph=true&h=300&w=458 "(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-ISOPROPYL-4-PHENYL-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE")
| SpectraBase Compound ID | 6tIZnrbdAdc |
|---|---|
| InChI | InChI=1S/C27H42NO2SSi.BF4/c1-8-32(9-2,10-3)30-27(24-17-13-11-14-18-24)26(23(4)5)21-22-31(29,28(6)7)25-19-15-12-16-20-25;2-1(3,4)5/h11-23,26-27H,8-10H2,1-7H3;/q+1;-1/b22-21-;/t26-,27-,31?;/m0./s1 |
| InChIKey | WNFHTSTUNGMYOK-OXYGRFPBSA-N |
| Mol Weight | 559.6 g/mol |
| Molecular Formula | C27H42BF4NO2SSi |
| Exact Mass | 559.27347 g/mol |
| Parent InChIKey | IHSQTJBZXQWHJI-LLKZRIMTSA-N |
| Enantiomer InChIKey | WNFHTSTUNGMYOK-RCXISARRSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
triethyl(((3R,4R,E)-2-methyl-4-phenyl-6-((R)-(N-methyl)-S-phenylsulfonimidoyl)hex-5-en-3-yl)oxy)silane
Allyl (5S,6S,7R,8R)-5-azido-6-methyl-7-hydroxy-8-[(tert-butyldimethylsilyl)oxy]-8-phenyloct-2(E)-enoate
N-{(1R,2S)-2-[(R)-1-tert-Butyldimethylsiloxy-1-phenylmethyl]-1-methylbutyl]-(2S)-2-methoxymethyl-tetrahydro-1H-1-pyrrolylamine
(3E)-1-phenyl-2,4-bis(phenylsulfanyl)-4-(trimethylsilyl)-3-butenyl trimethylsilyl ether
(S)-N-[(1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-ethyl]-3-dibenzylamino-N-methyl-butyramide
3,7-bis[2'-(t-Butyldimethylsilyloxy)-1'-methyl-2'-phenylethyl]-3,7-diazabicyclo[3.3.1]nonan-9-one
3-[1',1'-Dimethyl-2-propenyloxy)propyl]-2-phenyl-3-[(trimethylsilyl)oxy]oxetane
(-)-(4R,5R)-TRIETHYL-(4-ISOPROPYL-3-METHYL-5-PHENYL-4,5-DIHYDRO-FURAN-2-YL)-SILANE
(2RS,3RS)-2,3-Diphenyl-3-[(trimethylsilyl)oxy] oxetane
(-)-(2-S,3-R,6-S,R(S))-6-METHYL-2-PHENYL-3-(PARA-TOLYLSULFINYL)-3,6-DIHYDRO-2H-PYRAN
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides | Journal of the American Chemical Society | 2002 |