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[RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-L-IDITOL]-BF4

Compound with spectra: 2 NMR

[RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-L-IDITOL]-BF4
SpectraBase Compound ID 6RFSu5UlHfd
InChI InChI=1S/C62H66O5P2Si2.C8H8.BF4.Rh/c1-61(2,3)70(53-39-23-11-24-40-53,54-41-25-12-26-42-54)63-47-57-59(66-68(49-31-15-7-16-32-49)50-33-17-8-18-34-50)60(67-69(51-35-19-9-20-36-51)52-37-21-10-22-38-52)58(65-57)48-64-71(62(4,5)6,55-43-27-13-28-44-55)56-45-29-14-30-46-56;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h7-46,57-60H,47-48H2,1-6H3;1-2,7-8H2;;/q;;2*-1/p+2/t57-,58-,59+,60+;;;/m1.../s1
InChIKey YYXUCPPYLMCRCW-SEOCYRNBSA-P
Mol Weight 1305.2 g/mol
Molecular Formula C70H76BF4O5P2RhSi2
Exact Mass 1304.37906 g/mol
Parent InChIKey KNZZTYPFXHBHBC-JKJAYACKSA-P
Enantiomer InChIKey YYXUCPPYLMCRCW-PUNABGESSA-P

View Spectrum of [RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-L-IDITOL]-BF4

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of [RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-L-IDITOL]-BF4

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
[RH-(1,5-CYCLOOCTADIENE)-3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-D-MANNITOL]-BF4
Title Journal or Book Year
C2-Symmetric Diphosphinite Ligands Derived from Carbohydrates. The Strong Influence of Remote Stereocenters on Asymmetric Rhodium-Catalyzed Hydrogenation The Journal of Organic Chemistry 2004
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