5'-O-(TERT.-BUTYLDIPHENYLSILYL)-3'-O-[(2R,4S,5R)-3,4-DIMETHYL-5-PHENYL-1,3,2-OXAZAPHOSPHOLIDIN-2-YL]-THYMIDINE
Compound with spectra: 1 NMR
![5'-O-(TERT.-BUTYLDIPHENYLSILYL)-3'-O-[(2R,4S,5R)-3,4-DIMETHYL-5-PHENYL-1,3,2-OXAZAPHOSPHOLIDIN-2-YL]-THYMIDINE](/api/compound/6R1y0qFgtfw.png?ph=true&h=300&w=458 "5'-O-(TERT.-BUTYLDIPHENYLSILYL)-3'-O-[(2R,4S,5R)-3,4-DIMETHYL-5-PHENYL-1,3,2-OXAZAPHOSPHOLIDIN-2-YL]-THYMIDINE")
| SpectraBase Compound ID | 6R1y0qFgtfw |
|---|---|
| InChI | InChI=1S/C36H44N3O6PSi/c1-25-23-39(35(41)37-34(25)40)32-22-30(44-46-38(6)26(2)33(45-46)27-16-10-7-11-17-27)31(43-32)24-42-47(36(3,4)5,28-18-12-8-13-19-28)29-20-14-9-15-21-29/h7-21,23,26,30-33H,22,24H2,1-6H3,(H,37,40,41)/t26-,30+,31-,32-,33-,46?/m0/s1 |
| InChIKey | XQZYTTICAHQDLM-SXZQWXSGSA-N |
| Mol Weight | 673.8 g/mol |
| Molecular Formula | C36H44N3O6PSi |
| Exact Mass | 673.2737 g/mol |
| Enantiomer InChIKey | XQZYTTICAHQDLM-UKTDCRIKSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
5'-O-(TERT.-BUTYLDIPHENYLSILYL)-3'-O-[(2R,5R)-3-ISOPROPYL-5-PHENYL-1,3,2-OXAZAPHOSPHOLIDIN-2-YL]-THYMIDINE
DITHYMIDINYL-PHOSPHOROTHIOATE
AVHYLAHETOURAZ-KLBWRPGSSA-N
(S(P))-5'-O-DIMETHOXYTRITYL-THYMIDINE-3'-O-(SE-METHYL-METHANEPHOSPHONOSELENOLATE);FAST-(S(P))
(R(P))-5'-O-DIMETHOXYTRITYL-THYMIDINE-3'-O-(S-METHYL-METHANEPHOSPHONOTHIOLATE);SLOW-(R(P))
D-(G+6PT);MAJOR-ISOMER
3'-O-ACETYL-5'-(5'-O-TRITYLDEOXYTHYMID-3'-YLOXY(ANILIDO)PHOSPHORYL)DEOXYTHYMIDINE (DIASTEREOMER MIXTURE)
3'-O-ACETYL-5'-(5'-O-METHOXYTRITYLDEOXYTHYMID-3'-YLOXY(CYCLOHEXYLAMIDO)PHOSPHORYL)DEOXYTHYMIDINE
5'-O-PIVALOYLTHYMIDINE_3'-[2-METHOXYETHYL-2-ACETYL-2-BENZOYL-3-(4,4'-DIMETHOXYTRITYLOXY)-PROPYL]-PHOSPHATE;DIASTEREOMER_1
3',5'-O,O-BIS-(4,4'-DIMETHOXYTRITYL)-DITHYMIDYLYL-3',5'-SE-METHYL-PHOSPHOROSELENOATE
| Title | Journal or Book | Year |
|---|---|---|
| An Oxazaphospholidine Approach for the Stereocontrolled Synthesis of Oligonucleoside Phosphorothioates | Journal of the American Chemical Society | 2003 |