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[RH[(R)-DMBIPHEP]-[(R)-DABN]]SBF6

Compound with spectra: 2 NMR

[RH[(R)-DMBIPHEP]-[(R)-DABN]]SBF6
SpectraBase Compound ID 6PORmWVaCH5
InChI InChI=1S/C44H44P2.C20H14N2.6FH.Rh.Sb/c1-29-17-30(2)22-37(21-29)45(38-23-31(3)18-32(4)24-38)43-15-11-9-13-41(43)42-14-10-12-16-44(42)46(39-25-33(5)19-34(6)26-39)40-27-35(7)20-36(8)28-40;21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22;;;;;;;;/h9-28H,1-8H3;1-12,21-22H;6*1H;;/q;-2;;;;;;;+1;+5/p-4
InChIKey BYDOSRFPXWRWET-UHFFFAOYSA-J
Mol Weight 1257.8 g/mol
Molecular Formula C64H60F6N2P2RhSb
Exact Mass 1256.222893 g/mol
Parent InChIKey MZVYOUIYBKYZMD-UHFFFAOYSA-J

View Spectrum of [RH[(R)-DMBIPHEP]-[(R)-DABN]]SBF6

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CD2Cl2

View Spectrum of [RH[(R)-DMBIPHEP]-[(R)-DABN]]SBF6

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CD2Cl2
  • [RH[(R)-DMBIPHEP]-[(S)-DABN]]SBF6
Title Journal or Book Year
Racemic but Tropos (Chirally Flexible) BIPHEP Ligands for Rh(I)-Complexes:  Highly Enantioselective Ene-Type Cyclization of 1,6-Enynes Organic Letters 2004
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