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POTASSIUM-(2E,5Z,7Z)-(3S,4S)-2-[2-[3-(1-BENZYLOXY-8-BROMO-4-METHOXYMETHOXY-OCTA-5,7-DIENYL)]-3-HYDROXY-PHENYL]-VINYLTRIFLUOROBORATE

Compound with spectra: 1 NMR

POTASSIUM-(2E,5Z,7Z)-(3S,4S)-2-[2-[3-(1-BENZYLOXY-8-BROMO-4-METHOXYMETHOXY-OCTA-5,7-DIENYL)]-3-HYDROXY-PHENYL]-VINYLTRIFLUOROBORATE
SpectraBase Compound ID 6P92ZJoqZfH
InChI InChI=1S/C26H28BBrF3O6.K/c1-34-19-36-23(12-5-6-16-28)24(14-17-35-18-20-8-3-2-4-9-20)37-26(33)25-21(10-7-11-22(25)32)13-15-27(29,30)31;/h2-13,15-16,23-24,32H,14,17-19H2,1H3;/q-1;+1/b12-5-,15-13+,16-6-;/t23-,24-;/m0./s1
InChIKey FENGQNZDEGRKAO-HZGVTLDNSA-N
Mol Weight 623.3 g/mol
Molecular Formula C26H28BBrF3KO6
Exact Mass 622.075148 g/mol
Parent InChIKey BKAJJZXSBGMIAF-CMDQTOAJSA-N
Enantiomer InChIKey FENGQNZDEGRKAO-ITBAYNGRSA-N

View Spectrum of POTASSIUM-(2E,5Z,7Z)-(3S,4S)-2-[2-[3-(1-BENZYLOXY-8-BROMO-4-METHOXYMETHOXY-OCTA-5,7-DIENYL)]-3-HYDROXY-PHENYL]-VINYLTRIFLUOROBORATE

19F NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent ACETONE-D6
(3R)-3-{(1S)-1-Hydroxy-2-[(4-methoxybenzyl)oxy]ethyl}-13-methoxy-4,5,6,7-tetrahydro-2-benzoxacycloundecin-1(3H)-one
(3S,4S)-4-Hydroxy-14-methoxy-3-{[(4-methoxybenzyl)oxy]methyl}-3,4,5,6,7,8-hexahydro-1H-2-benzoxacyclododecin-1-one
(3S,5R,7R)-7-(Benzyloxy)-3-[3-(benzyloxy)propyl]-5-hydroxy-14-methoxy-3,4,5,6,7,8-hexahydro-1H-2-benzoxacyclododecin-1-one
PAECILOMYCIN_E;(4'-S,5'-R,6'-S,10'-S)-7',8'-DIHYDROZEAENOL
1H-2-Benzoxacyclotetradecin-1-one, 3,4,5,6,7,8,9,10-octahydro-7,8,9,16-tetrahydroxy-14-methoxy-3-methyl-
PAECILOMYCIN_F
1H-2-Benzoxacyclotetradecin-1,7(8H)-dione, 3,4,5,6,9,10-hexahydro-8,9,16-trihydroxy-14-methoxy-3-methyl-, [3S-(3R*,8R*,9R*,11E)]-
(3S)-14-(benzyloxy)-16-hydroxy-3-methyl-3,4,5,6,9,10-hexahydro-1H-2-benzoxacyclotetradecin-1,7(8H)-dione
ZEAENOL;(3S,5E,7S,8S,9S,11E)-3,4,7,8,9,10-HEXAHYDRO-7,8,9,16-TETRAHYDROXY-14-METHOXY-3-METHYL-1H-2-BENZOXACYCLOTETRADECIN-1-ONE
7-EPI-ZEAENOL
Title Journal or Book Year
Formal Total Synthesis of Oximidine II via a Suzuki-Type Cross-Coupling Macrocyclization Employing Potassium Organotrifluoroborates Journal of the American Chemical Society 2004
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