TRANS-(-)-[1R,3R,2(1E)]-3-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-[1-(N,N-DIISOPROPYLCARBAMOYLOXY)-ETHYLIDENE]-CYCLOPENTYL-N,N-DIISOPROPYLCARBAMATE
Compound with spectra: 1 NMR
![TRANS-(-)-[1R,3R,2(1E)]-3-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-[1-(N,N-DIISOPROPYLCARBAMOYLOXY)-ETHYLIDENE]-CYCLOPENTYL-N,N-DIISOPROPYLCARBAMATE](/api/compound/5apKWsf8tyc.png?ph=true&h=300&w=458 "TRANS-(-)-[1R,3R,2(1E)]-3-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-[1-(N,N-DIISOPROPYLCARBAMOYLOXY)-ETHYLIDENE]-CYCLOPENTYL-N,N-DIISOPROPYLCARBAMATE")
| SpectraBase Compound ID | 5apKWsf8tyc |
|---|---|
| InChI | InChI=1S/C27H52N2O5Si/c1-17(2)28(18(3)4)25(30)32-21(9)24-22(33-26(31)29(19(5)6)20(7)8)15-16-23(24)34-35(13,14)27(10,11)12/h17-20,22-23H,15-16H2,1-14H3/b24-21+/t22-,23-/m1/s1 |
| InChIKey | UVNGUSGPCZDJJM-JTTVLKEHSA-N |
| Mol Weight | 512.8 g/mol |
| Molecular Formula | C27H52N2O5Si |
| Exact Mass | 512.364549 g/mol |
| Enantiomer InChIKey | UVNGUSGPCZDJJM-RVTQGIHGSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(3aRS,4SR,5RS,6aSR)-3,3a,4,5,6,6a-Hexahydro-5-[(t-butyl)dimethylsilyloxy)-4-(3'-oxooct-1'-en-1'-yl)-2H-cyclopenta[b]furan-2-one
(1'R,3'S,1"'E)-5-{1',3'-Bistriethylsilyloxy-[furan-2"(5"H)-on-4"-yl]propyl}-5-(2"'-iodoethenyl)-2,2-dimethyl-1,3-dioxane
(-)-(1R,5R,6S)-5,6-BIS-([(TERT.-BUTYL)-DIMETHYLSILYL]-OXY)-2-OXO-CYCLOHEX-3-EN-1-YL-ACETATE
3,4,6-TRI-O-BENZYL-2-TERT.-BUTYL-DIMETHYLSILYL-OXYMETHYL-D-GLUCAL
5alpha-{[(tert-Butyl)dimethylsilyl]oxy}-2alpha-{(E,E)-4-methyl-6-{[(RS)-tetrahydro-2H-pyran-2-y1]-oxy}hexa-1,4-dienyl)-2-methylcyclopentylidene}-N,N-dimethylacetamide
{(Z)-5beta-{[(tert-Butyl)dimethylsilyl]oxy}-2alpha-{(E,E)-4-methyl-6-{[(RS)-tetrahydro-2H-pyran-2-y1]-oxy}hexa-1,4-dienyl)-2-methylcyclopentylidene}-N,N-dimethylacetamide
2,2-Dimethyl-5-[(1R,3S)-3-(5-oxidanylidene-2H-furan-3-yl)-1,3-bis(triethylsilyloxy)propyl]-1,3-dioxane-5-carbaldehyde
1-(TRIMETHYLSILYLETHYNYL)-3,4,6-TRI-O-TRIISOPROPYLSILYL-GLUCAL
1-PENTYN-1-YL-3,4,6-TRI-O-TRIISOPROPYLSILYL-GLUCAL
| Title | Journal or Book | Year |
|---|---|---|
| Synthesis of an Ethynyl Carbamate and Application for Enantioselective Cyclocarbolithiation | Organic Letters | 2002 |