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3,5-BIS-[[3,3'-BIS-(TRIMETHYLSILYL)-1,1'-BIPHENYL-2,2'-DIYL]-PHOSPHITE]-6-DEOXY-1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE

Compound with spectra: 2 NMR

3,5-BIS-[[3,3'-BIS-(TRIMETHYLSILYL)-1,1'-BIPHENYL-2,2'-DIYL]-PHOSPHITE]-6-DEOXY-1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE
SpectraBase Compound ID 539pVdF90T6
InChI InChI=1S/C45H62O9P2Si4/c1-28(49-55-50-38-29(20-16-24-33(38)57(4,5)6)30-21-17-25-34(39(30)51-55)58(7,8)9)37-42(43-44(46-37)48-45(2,3)47-43)54-56-52-40-31(22-18-26-35(40)59(10,11)12)32-23-19-27-36(41(32)53-56)60(13,14)15/h16-28,37,42-44H,1-15H3/t28-,37-,42+,43-,44-/m1/s1
InChIKey RAENSLTYNWBRHK-SUXXVPJFSA-N
Mol Weight 921.3 g/mol
Molecular Formula C45H62O9P2Si4
Exact Mass 920.294614 g/mol
Enantiomer InChIKey RAENSLTYNWBRHK-KYUTYNNVSA-N

View Spectrum of 3,5-BIS-[[3,3'-BIS-(TRIMETHYLSILYL)-1,1'-BIPHENYL-2,2'-DIYL]-PHOSPHITE]-6-DEOXY-1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent Unknown

View Spectrum of 3,5-BIS-[[3,3'-BIS-(TRIMETHYLSILYL)-1,1'-BIPHENYL-2,2'-DIYL]-PHOSPHITE]-6-DEOXY-1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent Unknown
3,5-BIS-[(3,3'-BIS-(TRIMETHYLSILYL)-1,1'-BIPHENYL-2,2'-DIYL)-PHOSPHITE]-6-DEOXY-1,2-O-ISOPROPYLIDENE-ALPHA-D-ALLOFURANOSE
1,2-O-ISOPROPYLIDENEGLYCEROL, 3-DIETHYLAMIDO(1,2;5,6-DI-O-ISOPROPYLIDEN-D-GLUCOFURANOSO)PHOSPHATE
3,3,7,7-TETRAMETHYL-1-[1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSYLOXY]-2,8-DIOXA-5-AZA-1-PHOSPHA(V)-BICYCLO-[3.3.0]-OCTANE
6-Deoxy-6-(4'-methyl-2'-quinoyl)-1,2:5,6-di-O-isopropylidene-.alpha.,D-galactopyranose
METHYL-2,3-O,O-ISOPROPYLIDENE-4-O-[METHYL(2,3,4-TRI-O-ACETYL-BETA-D-MANNOPYRANOSYL)URONATE]-ALPHA-L-RHAMNOPYRANOSIDE
METHYL-2,3-O,O-ISOPROPYLIDENE-4-O-[METHYL(2,3,4-TRI-O-ACETYL-ALPHA-D-MANNOPYRANOSYL)URONATE]-ALPHA-L-RHAMNOPYRANOSIDE
BENZYL(D,L-2,3-ISOPROPYLIDENEDIOXY-1-PROPOXY)(1,2;5,6-DICYCLOHEXYLIDENE-ALPHA-D-GLUCOFURANOSO-3)PHOSPHATE
1,2:3,5-Di-O-isopropylidene-6-O-(2,3,4,6-tetra-O-acetyl.beta.-D-glucopyranosyl).alpha.-D-glucofuranose
5,6-Dideoxy-1,2-O-isopropylidene-3-O-benzyl-5-[(R and S)-(methoxy)phenylphosphinyl]-.beta.-D-arabino-hexofuranose
(5R,5S)-3-O-Benzyl-5,6-dideoxy-1,2-O-isopropylidene-5[(R,S)-(methoxy)phenylphosphinyl]-.alpha.,D-ribo-hexofuranose
Title Journal or Book Year
Chiral Diphosphites Derived from d-Glucose:  New Highly Modular Ligands for the Asymmetric Catalytic Hydrogenation The Journal of Organic Chemistry 2002
Other Resources
Unknown Identification

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