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(-)-(1R,4R,5R,6R)-5-exo,6-endo-bis{[(tert-butyl)dimethylsilyl]oxy}-7-oxabicyclo[2.2.1]heptan-2-one

Compound with spectra: 1 NMR

(-)-(1R,4R,5R,6R)-5-exo,6-endo-bis{[(tert-butyl)dimethylsilyl]oxy}-7-oxabicyclo[2.2.1]heptan-2-one
SpectraBase Compound ID 4Al5t64aWO4
InChI InChI=1S/C18H36O4Si2/c1-17(2,3)23(7,8)21-15-13-11-12(19)14(20-13)16(15)22-24(9,10)18(4,5)6/h13-16H,11H2,1-10H3/t13-,14+,15-,16-/m0/s1
InChIKey KYMJNBKLDROJQG-FZKCQIBNSA-N
Mol Weight 372.7 g/mol
Molecular Formula C18H36O4Si2
Exact Mass 372.215213 g/mol
Enantiomer InChIKey KYMJNBKLDROJQG-QKPAOTATSA-N

View Spectrum of (-)-(1R,4R,5R,6R)-5-exo,6-endo-bis{[(tert-butyl)dimethylsilyl]oxy}-7-oxabicyclo[2.2.1]heptan-2-one

13C NMR Spectrum
Copyright Copyright © 2016-2025 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
7-Oxabicyclo[2.2.1]heptan-2-one, 5,6-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, [1R-(5-exo,6-endo)]-
7-Oxabicyclo[2.2.1]heptan-2-one, 5,6-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, [1R-(exo,exo)]-
(+)-(1R,4R,5R,6S)-5-EXO,6-EXO-BIS-([(TERT.-BUTYL)-DIMETHYLSILYL]-OXY)-7-OXABICYCLO-[2.2.1]-HEPTAN-2-ONE
(-)-METHYL-2,5-ANHYDRO-3,4-BIS-[(TERT.-BUTYL)-DIMETHYLSILYL]-D-ALLONATE
Saccharic acid, .gamma.-lactone, tetra-TMS
(-)-1L-3-O-ACETYL-1,2-BIS-([(TERT.-BUTYL)-DIMETHYLSILYL]-OXY)-CYCLOHEX-5-ENE-1,2,3,4/0-TETROL
BENZYL-2,3-DI-O-(TERT.-BUTYLDIMETHYLSILYL)-4-CYANO-4-DEOXY-ALPHA-D-ARABINOSIDE
(4.beta.-(tert-Butyldimethylsilyloxy)-2.beta,6.beta.-bis(hydroxymethyl)-5.beta.-hydroxytetrahydropyran-3.alpha.-yl)pivaloate
(4.alpha.-(tert-Butyldimethylsilyloxy)-2.beta.,6,beta.-bis-hydroxymethyl-5.beta.-hydroxytetrahydropyran-3.alpha.-yl)pivaloate
(2S,3R,4R,5S,6R)-4-(tert-butyldimethylsiloxy)-2,6-bishydroxymethyl-5-hydroxy-tetrahydropyran-3-yl)pivaloate
methyl (2S)-2-[(2S,3S,4R)-5-oxo-3,4-bis(trimethylsilyloxy)tetrahydrofuran-2-yl]-2-trimethylsilyloxy-acetate
Title Journal or Book Year
Total Syntheses of (?)-Conduritol B ((?)-1L-Cyclohex-5-ene-1,3/2,4-tetrol) and of (+)-Conduritol F((+)-1D-Cyclohex-5-ene-1,2,4/3-tetrol). Determination of the Absolute Configuration of (+)-Leucanthemito Helvetica Chimica Acta 1990
7-Oxabicyclo[2.2.1]heptan-2-one, 5,6-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, [1R-(5-exo,6-endo)]-
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