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ISOROGIOLEYGENINE-A;(+)-(1R,2R,3S,5R,7S)-2-(BROMOMETHYL)-5-[(Z)-1-CHLOROHEX-3-EN-5-YNYL]-3-ETHYL-4,8-DIOXABICYCLO-[5.1.0]-OCTANE

Compound with spectra: 1 NMR

ISOROGIOLEYGENINE-A;(+)-(1R,2R,3S,5R,7S)-2-(BROMOMETHYL)-5-[(Z)-1-CHLOROHEX-3-EN-5-YNYL]-3-ETHYL-4,8-DIOXABICYCLO-[5.1.0]-OCTANE
SpectraBase Compound ID 3tDL6ub2iRX
InChI InChI=1S/C15H20BrClO2/c1-3-5-6-7-11(17)13-8-14-15(19-14)10(9-16)12(4-2)18-13/h1,5-6,10-15H,4,7-9H2,2H3/b6-5+/t10-,11-,12+,13?,14+,15-/m1/s1
InChIKey WWXDSNUMWFIGFH-BQIQLDJPSA-N
Mol Weight 347.68 g/mol
Molecular Formula C15H20BrClO2
Exact Mass 346.033521 g/mol
Enantiomer InChIKey WWXDSNUMWFIGFH-AOTWJBFLSA-N

View Spectrum of ISOROGIOLEYGENINE-A;(+)-(1R,2R,3S,5R,7S)-2-(BROMOMETHYL)-5-[(Z)-1-CHLOROHEX-3-EN-5-YNYL]-3-ETHYL-4,8-DIOXABICYCLO-[5.1.0]-OCTANE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
2-(bromomethyl)-5-[(Z)-1-chlorohex-3-en-5-ynyl]-3-ethyl-4,8-dioxabicyclo[5.1.0]octane
ROGIOLENYNE-A;(-)-(1R*,2S*,3R*,5S*,7S*)-2-(BROMOMETHYL)-5-[(Z)-1-CHLOROHEX-3-EN-5-YNYL]-3-ETHYL-4,8-DIOXABICYCLO-[5.1.0]-OCTANE
ROGIOLENYNE-B;(-)-(2R*,3R*,4R*,5R*,7S*)-3-(BROMOMETHYL)-5-CHLORO-7-[(Z)-1-CHLOROHEX-3-EN-5-YNYL]-2-ETHYLOXEPAN-4-OL
2,7-Dioxabicyclo[4.2.1]nonane, 5-bromo-3-(1-bromopropyl)-8-(2-penten-4-ynyl)-, [1R-[1.alpha.,3.alpha.(S*),5.alpha.,6.alpha.,8.beta.(E)]]-
NEOISOPRELAUREFUCIN
LAURENDECUMENYNE_B;(3-E)-6:10,9:13-BISEPOXY-12-BROMO-7-CHLOROPENTADECA-3-EN-1-YNE
(3E)-Dactomelyne
(2S,3R,4aR,6S,7S,8aR)-3-bromanyl-7-chloranyl-2-ethyl-6-[(Z)-pent-2-en-4-ynyl]-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran
10-oxotricyclo[5.4.0.0(2,9)]undecane-8-carboxylic acid-3,3,7-trimethyl
[(2R,3R,5R)-5-{4(S)-2,2-dimethyl[1,3]dioxolan-4-yl}-2-[pent-2(E)-en-4-ynyl]-tetrahydrofuran-3-yl acetate
Title Journal or Book Year
Rogiolenyne D, the likely immediate precursor of rogiolenyne A and B, branched C15 acetogenins isolated from the red seaweedLaurencia microcladia of II Rogiolo. Conformation and absolute configuration in the whole series Helvetica Chimica Acta 1992
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