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tert-butyl-[[(1S,4S,7S)-7-[(2S)-1-(tert-butyl-dimethylsilyl)oxypropan-2-yl]-4-methyl-1-cyclohept-2-enyl]oxy]-dimethylsilane
SpectraBase Compound ID 3oh0BqekD19
InChI InChI=1S/C23H48O2Si2/c1-18-13-15-20(19(2)17-24-26(9,10)22(3,4)5)21(16-14-18)25-27(11,12)23(6,7)8/h14,16,18-21H,13,15,17H2,1-12H3/t18-,19+,20-,21-/m0/s1
InChIKey LKYTVHICSYJBME-WOZUAGRISA-N
Mol Weight 412.8 g/mol
Molecular Formula C23H48O2Si2
Exact Mass 412.319284 g/mol
Enantiomer InChIKey LKYTVHICSYJBME-PLACYPQZSA-N
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
Title Journal or Book Year
A Novel Synthetic Method of the (±)-(3aα,8aα)-Ethyl 8β-Hydroxy-6β-methyl-2-oxooctahydro-2H-cyclohepta[b]furan-3α- carboxylate and Its Chemical Transformation to (±)-(3aα,8aα)-3α,6β-Dimethyl-3,3a,4,5,6,8a-hexahydro-2H- cyclohepta[b]furan-2-one, (+)- and (−)-7β-(2-Acetoxy-1α-methylethyl)-4β-methyl-2-cyclohepten-1β-ol, and (+)- and (−)-7β-(2-Acetoxy-1α-methylethyl)-4β-methyl-2-cyclohepten-1-one. Possible Common Synthetic Intermediates for Pseudoguaianolides, 4,5-Secopseudoguaianolides, Guaianolides, 4,5-Secoguaianolides, and Octalactins The Journal of Organic Chemistry 1998
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