(-)-(S)-N,N-DIMETHYLAMINO-S-[(1E,5Z)-(3R,4S)-3-CYCLOHEXYL-6-PHENYL-4-[(TRIETHYLSILYL)-OXY]-HEXA-1,5-DIENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE
Compound with spectra: 1 NMR
![(-)-(S)-N,N-DIMETHYLAMINO-S-[(1E,5Z)-(3R,4S)-3-CYCLOHEXYL-6-PHENYL-4-[(TRIETHYLSILYL)-OXY]-HEXA-1,5-DIENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE](/api/compound/3ilxUewVWl1.png?ph=true&h=300&w=458 "(-)-(S)-N,N-DIMETHYLAMINO-S-[(1E,5Z)-(3R,4S)-3-CYCLOHEXYL-6-PHENYL-4-[(TRIETHYLSILYL)-OXY]-HEXA-1,5-DIENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE")
| SpectraBase Compound ID | 3ilxUewVWl1 |
|---|---|
| InChI | InChI=1S/C32H48NO2SSi.BF4/c1-6-37(7-2,8-3)35-32(25-24-28-18-12-9-13-19-28)31(29-20-14-10-15-21-29)26-27-36(34,33(4)5)30-22-16-11-17-23-30;2-1(3,4)5/h9,11-13,16-19,22-27,29,31-32H,6-8,10,14-15,20-21H2,1-5H3;/q+1;-1/b25-24+,27-26-;/t31-,32+,36?;/m1./s1 |
| InChIKey | WEUCSYHLJIHKHF-NPBICDIDSA-N |
| Mol Weight | 625.7 g/mol |
| Molecular Formula | C32H48BF4NO2SSi |
| Exact Mass | 625.32042 g/mol |
| Parent InChIKey | CHMLFXFMWFQPMA-NGQVVFKJSA-N |
| Enantiomer InChIKey | WEUCSYHLJIHKHF-QZNVDKQKSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-CYCLOHEXYL-6-PHENYL-4-[(TRIETHYLSILYL)-OXY]-HEX-1-EN-YNYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE
(Z)-7-[(1R,2R,3R)-3-[tert-butyl(dimethyl)silyl]oxy-2-[(E,3S)-3-[tert-butyl(dimethyl)silyl]oxyoct-1-enyl]-5-keto-cyclopentyl]hept-5-enoic acid methyl ester
alpha-[4-exo-(3-cyclohexyl-3S-hydroxy-trans-propenyl)-5-endo-hydroxy-(Z)-3alpha,6aalpha-2-pentalenylidene]-m-toluic acid
(.alpha.S,exo,exo)-.alpha.-Methyl-6-[(triethylsilyl]oxy]bicyclo[2.2.1]heptan-2-methol.alpha.-(4-Methylbenzenesulfonate)
(,alpha.R,exo,exo)-.alpha.-Methyl-6-[(triethylsilyl]oxy]bicyclo[2.2.1]heptan-2-methol.alpha.-(4-Methylbenzenesulfonate)
Cyclopentanepropanoic acid, 3,5-bis[(trimethylsilyl)oxy]-2-[3-[(trimethylsilyl)oxy]-1-octenyl]-, methyl ester, [1R-[1.alpha.,2.beta.(1E,3S*),3.alpha.,5.alpha.]]-
DMIPS-ether of prostaglandin F-2.alpha.-methyl ester
7-(2-(3-oxo-8-(trimethylsiloxy)octyl)-3,5-di(trimethylsiloxy)cyclopenyl)-5(Z)-heptenoic acid methyl ester
1-Naphthalenesulfonamide, 4-fluoro-N-[2-(tricyclo[3.3.1.1(3,7)]dec-1-yloxy)ethyl]-
#25;(3-S,7-S,8-R,9-R)-8-HYDROXY-7-(METHOXYMETHOXY)-3-METHYL-9-[(TRIETHYLSILYL)-OXY]-3,4,5,6,7,8,9,10-OCTAHYDRO-1H-2-BENZOXACYCLOTETRADECIN-1-ONE
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides | Journal of the American Chemical Society | 2002 |