[[(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-1,5-DIYL]-DI-(R)-ETHYLIDENE]-BIS-[DIPHENYLPHOSPHINE]
Compound with spectra: 1 NMR
![[[(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-1,5-DIYL]-DI-(R)-ETHYLIDENE]-BIS-[DIPHENYLPHOSPHINE]](/api/compound/3dzyCtAhV5s.png?ph=true&h=300&w=458 "[[(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-1,5-DIYL]-DI-(R)-ETHYLIDENE]-BIS-[DIPHENYLPHOSPHINE]")
| SpectraBase Compound ID | 3dzyCtAhV5s |
|---|---|
| InChI | InChI=1S/C33H36O2P2/c1-25(36(27-17-9-5-10-18-27)28-19-11-6-12-20-28)31-32(35-33(3,4)34-31)26(2)37(29-21-13-7-14-22-29)30-23-15-8-16-24-30/h5-26,31-32H,1-4H3/t25-,26-,31-,32-/m1/s1 |
| InChIKey | XFIALTWJZRBKQY-QBQKZGEHSA-N |
| Mol Weight | 526.6 g/mol |
| Molecular Formula | C33H36O2P2 |
| Exact Mass | 526.219054 g/mol |
| Enantiomer InChIKey | XFIALTWJZRBKQY-MCZNPFQCSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
2,5-bis(diphenylphosphino)-1,4.3,6-dianhydro-2,5-dideoxy-L-iditol
[(4R,5R)-5-(diphenylphosphanylmethyl)-2-methyl-2-phenyl-1,3-dioxolan-4-yl]methyl-diphenyl-phosphane
(R,R)-4,5-Bis(diphenylphosphinomethyl)-2-(2'-hydroxyphenyl)-1,3-dioxolane
3-Pentanol, 2-(diphenylphosphinyl)-4-methoxy-3-methyl-
5-Diphenylphosphinoyl-6-hydroxynonan-2-one ethylene acetal
2-Oxepanone, 7-[1-(diphenylphosphinyl)ethyl]-, (R*,S*)-(.+-.)-
2-Oxepanone, 7-[1-(diphenylphosphinyl)ethyl]-, (R*,R*)-(.+-.)-
(2R,3R)-3-diphenylphosphoryl-2-hydroxy-enanthic acid methyl ester
5-Diphenylphosphinoyl-6-hydroxyoctan-2-one ethylene acetal
(2E,4R*,5S*)-5-Diphenyphosphinoyl-3-methylnon-2-en-4-ol
| Title | Journal or Book | Year |
|---|---|---|
| Ligand Substituent Effects on Asymmetric Induction. Effect of Structural Variations of the DIOP Ligand on the Rh-Catalyzed Asymmetric Hydrogenation of Enamides | Organic Letters | 2000 |