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(4R,6S)-6-(2,2-DIBROMOVINYL)-4-(DIMETHYLPHENYLSILYL)-3-[(S)-1-HYDROXY-2-(4-METHOXYBENZYLOXY)-ETHYL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-2-ONE

Compound with spectra: 1 NMR

(4R,6S)-6-(2,2-DIBROMOVINYL)-4-(DIMETHYLPHENYLSILYL)-3-[(S)-1-HYDROXY-2-(4-METHOXYBENZYLOXY)-ETHYL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-2-ONE
SpectraBase Compound ID 3adyLuWAmui
InChI InChI=1S/C25H30Br2O5Si/c1-30-18-11-9-17(10-12-18)15-31-16-21(28)24-22(13-19(14-23(26)27)32-25(24)29)33(2,3)20-7-5-4-6-8-20/h4-12,14,19,21-22,24,28H,13,15-16H2,1-3H3/t19-,21+,22+,24-/m0/s1
InChIKey MABCKSYMXJXSQE-BQUSRXHISA-N
Mol Weight 598.4 g/mol
Molecular Formula C25H30Br2O5Si
Exact Mass 596.022927 g/mol
Enantiomer InChIKey MABCKSYMXJXSQE-LKFPXLSTSA-N

View Spectrum of (4R,6S)-6-(2,2-DIBROMOVINYL)-4-(DIMETHYLPHENYLSILYL)-3-[(S)-1-HYDROXY-2-(4-METHOXYBENZYLOXY)-ETHYL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-2-ONE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(S)-1-[(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-4-(DIMETHYLPHENYLSILYL)-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYL-OXY)-ETHAN-1-OL
4H-1,3-Benzodioxin-4-one, 2-(1,1-dimethylethyl)-5-(dimethylphenylsilyl)hexahydro-, [2S-(2.alpha.,4a.alpha.,5.beta.,8a.beta.)]-
(1'S,2R,5R,6R)-2-TERT.-BUTYL-5-(1'-DIMETHYLPHENYLSILYLBENZYL)-6-METHYL-1,3-DIOXAN-4-ONE
2-tert-Butyl-5-[[dimethyl(phenyl)silyl](phenyl)methyl]-6-methyl-1,3-dioxan-4-one
(1a,2a,5a,7a,9a)-2-bromo-3,3-dimethyl-4-oxatricyclo[3.2.2.02,7]non-9-yl benzoate
2',3'-DIDEOXY-2'-ALPHA-C-CARBOXYMETHYL-5'-O-DIMETHOXYTRITYL-URIDINE
6"-Dihydro-3,5-isopropylidene-6"-O-(4-methoxybenzyl) Leuconolide A1
(7,8-trans, 8,8'-trans, 7',8'-cis)-7-(5"'-Methoxy-3''',4'''-methylenedioxyphenyl)-7'-(4"hydroxy-3",5"-dimethoxyphenyl)-8-(acetoxymethyl)-8'-(hydroxymethyl)-tetrahydroifuran
(2R*,5R*,6R*)-3-(TERT.-BUTYLDIMETHYLSILOXY)-5-(DIMETHYLPHENYLSILYL)-6-FORMYL-5,6,7,8-TETRAHYDRO-2H-OXOCINE-2-CARBOXYLIC-ACID-METHYLESTER
{(2S,3R)-5-Hydroxy-2-[(R)-(4-methoxy-benzyloxy)-((4S,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-methyl]-tetrahydro-furan-3-yl}-acetic acid tert-butyl ester
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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