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(+/-)-7-BETA-[2-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1-ALPHA-METHYLETHYL]-4-BETA-METHYL-2-CYCLOHEPTEN-1-ONE
SpectraBase Compound ID 2A0EkjoIJwt
InChI InChI=1S/C17H32O2Si/c1-13-8-10-15(16(18)11-9-13)14(2)12-19-20(6,7)17(3,4)5/h9,11,13-15H,8,10,12H2,1-7H3/t13-,14+,15-/m0/s1
InChIKey JRNSTJHSUKCACO-ZNMIVQPWSA-N
Mol Weight 296.5 g/mol
Molecular Formula C17H32O2Si
Exact Mass 296.217157 g/mol
Enantiomer InChIKey JRNSTJHSUKCACO-QLFBSQMISA-N
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
Title Journal or Book Year
A Novel Synthetic Method of the (±)-(3aα,8aα)-Ethyl 8β-Hydroxy-6β-methyl-2-oxooctahydro-2H-cyclohepta[b]furan-3α- carboxylate and Its Chemical Transformation to (±)-(3aα,8aα)-3α,6β-Dimethyl-3,3a,4,5,6,8a-hexahydro-2H- cyclohepta[b]furan-2-one, (+)- and (−)-7β-(2-Acetoxy-1α-methylethyl)-4β-methyl-2-cyclohepten-1β-ol, and (+)- and (−)-7β-(2-Acetoxy-1α-methylethyl)-4β-methyl-2-cyclohepten-1-one. Possible Common Synthetic Intermediates for Pseudoguaianolides, 4,5-Secopseudoguaianolides, Guaianolides, 4,5-Secoguaianolides, and Octalactins The Journal of Organic Chemistry 1998
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