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(E)-(1SR,2SR,3RS,5SR)-5-(4ï-METHOXYCARBONYL)-BUTYLIDENE-3-TERT.-BUTYLDIMETHYLSILYLOXY-2-CYANOBICYCLO-[3.3.0]-OCTANE

Compound with spectra: 3 NMR

(E)-(1SR,2SR,3RS,5SR)-5-(4ï-METHOXYCARBONYL)-BUTYLIDENE-3-TERT.-BUTYLDIMETHYLSILYLOXY-2-CYANOBICYCLO-[3.3.0]-OCTANE
SpectraBase Compound ID 20bk6PZgkRq
InChI InChI=1S/C21H35NO3Si/c1-21(2,3)26(5,6)25-19-13-16-11-15(12-17(16)18(19)14-22)9-7-8-10-20(23)24-4/h9,16-19H,7-8,10-13H2,1-6H3/b15-9+/t16-,17-,18+,19+/m1/s1
InChIKey OSZNZLIKEMKKEF-PNNZMNCVSA-N
Mol Weight 377.6 g/mol
Molecular Formula C21H35NO3Si
Exact Mass 377.238621 g/mol
Enantiomer InChIKey OSZNZLIKEMKKEF-PRLHRQKHSA-N

View Spectrum of (E)-(1SR,2SR,3RS,5SR)-5-(4ï-METHOXYCARBONYL)-BUTYLIDENE-3-TERT.-BUTYLDIMETHYLSILYLOXY-2-CYANOBICYCLO-[3.3.0]-OCTANE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (E)-(1SR,2SR,3RS,5SR)-5-(4ï-METHOXYCARBONYL)-BUTYLIDENE-3-TERT.-BUTYLDIMETHYLSILYLOXY-2-CYANOBICYCLO-[3.3.0]-OCTANE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (E)-(1SR,2SR,3RS,5SR)-5-(4ï-METHOXYCARBONYL)-BUTYLIDENE-3-TERT.-BUTYLDIMETHYLSILYLOXY-2-CYANOBICYCLO-[3.3.0]-OCTANE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • (Z)-(1SR,2SR,3RS,5SR)-5-(4ï-METHOXYCARBONYL)-BUTYLIDENE-3-TERT.-BUTYLDIMETHYLSILYLOXY-2-CYANOBICYCLO-[3.3.0]-OCTANE;ISOMER_1
  • (Z)-(1SR,2SR,3RS,5SR)-5-(4ï-METHOXYCARBONYL)-BUTYLIDENE-3-TERT.-BUTYLDIMETHYLSILYLOXY-2-CYANOBICYCLO-[3.3.0]-OCTANE;ISOMER_2
5-[(3aS,4S,5R,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-4-cyano-hexahydro-pentalen-(2Z)-ylidene]-pentanoic acid methyl ester
8-(tert-Butyldimethylsiloxy)-8,9-di(hydroxymethyl)bicyclo[4.3.0]nonane
(1S,5S,6S,7R)-6-(hydroxymethyl)-(E)-3-[4-(tert-butoxycarbonyl)-3-oxabutylidene]-7-[(tetrahydropyranyl)oxy]bicyclo[3.3.0]octane
alpha-[4-exo-(3-cyclohexyl-3S-hydroxy-trans-propenyl)-5-endo-hydroxy-(Z)-3alpha,6aalpha-2-pentalenylidene]-m-toluic acid
(1'S*,2'S*,4a'R*,8'S*,8a'S*)-8'-(tert-butyldimethylsiloxy)-2'-methyl-1',2',4a',5',6',7',8',8a'-octahydronaphthalene-1'-propanol
5-(2-(3-(methoxyimino)-5-(trimethylsiloxycarbonyl)pentyl)-3,5-di(trimethylsiloxy)cyclopenyl)-3(Z)-pentenoic acid methyl ester
JQYCUZSNFCTKQC-VCHRRKICSA-N
JQYCUZSNFCTKQC-AZKZNFPZSA-N
Cyclopentaneacetic acid, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-oxo-2-(3-oxo-1-octenyl)-, methyl ester, [1.alpha.,2.beta.(E),3.beta.]-(.+-.)-
Methyl 2-[2-(2-Propenyl]-3-[(tert-butyldiphenylsilyl)oxy]cyclopentyl]acetate
Title Journal or Book Year
Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of a (±)-carbacyclin analogue with the geometry of the exocyclic double bond controlled by the protodesilylation of an allylsilane Journal of the Chemical Society, Perkin Transactions 1 1998
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