#10M/11M;SYN-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,5S)-2,5-DI-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-(METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENO
Compound with spectra: 1 NMR
![#10M/11M;SYN-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,5S)-2,5-DI-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-(METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENO](/api/compound/19JwnXnhl7u.png?ph=true&h=300&w=458 "#10M/11M;SYN-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,5S)-2,5-DI-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-(METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENO")
| SpectraBase Compound ID | 19JwnXnhl7u |
|---|---|
| InChI | InChI=1S/C42H57NO5Si/c1-32(2)39(23-16-28-48-49(42(3,4)5,37-19-11-9-12-20-37)38-21-13-10-14-22-38)40(27-24-33-17-15-18-36(29-33)47-8)41(44)43-34(30-45-6)25-26-35(43)31-46-7/h9-15,17-22,24,27,29,34-35,39-40H,1,16,23,25-26,28,30-31H2,2-8H3/b27-24+/t34-,35-,39?,40?/m0/s1 |
| InChIKey | ALYAILZLYSFIAV-FIXNCARTSA-N |
| Mol Weight | 684.0 g/mol |
| Molecular Formula | C42H57NO5Si |
| Exact Mass | 683.4006 g/mol |
| Enantiomer InChIKey | ALYAILZLYSFIAV-SKSKLYNKSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#8M;ANTI-(2R,3R)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,5S)-2,5-DI-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENT
#9M;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,5S)-2,5-DI-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENT
#18M;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,5S)-2,5-DI-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL-4-PENTE
(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-HYDROXYPROPYL)-2-[(E)-2-(3-(METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENONE-1
(2S,3S)-2-[[tert-butyl(diphenyl)silyl]oxymethyl]-3-[2-(2-methyl-1,3-dioxolan-2-yl)ethyl]-5-oxo-1-pyrrolidinecarboxylic acid tert-butyl ester
(+)-(3R,5R)-3-Acetyl-N-(benzyloxycarbonyl)-5-(-oxymethyl)-2-pyrrolidone, enol form
2-[(t-Butyldiphenylsilyl)oxy]pentanoyl [3'-{2",2"-dimethyl-5"-[5"'-(4-methoxybenzyloxy)-3"'-methylpent-3''-enyl]-[1",3"]-dioxolan-4"-yl}-2'-[(methoxy)methoxypropyl)-amide
N(DELTA)-(5-TERT.-BUTYLDIPHENYLSILYL-ALPHA-D-RIBOFURANOSYL)-N(ALPHA)-BENZYLOXYCARBONYL-GLUTAMINE-BENZYLESTER
2'-MERCAPTOETHYL-4-AZIDO-3-O-BENZYL-6-O-TERT.-BUTYLDIPHENYLSILYL-1,2,4-TRIDEOXY-1-THIO-BETA-D-ARABINOSE-HEXOSIDE
2,3,4-TRI-O-BENZYL-6-O-TERT.-BUTYLDIPHENYLSILYL-ALPHA-D-MANNOPYRANOSIDE
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |