Spectra for:
Laure C. Bouchez, Cotinica Craita, Pierre Vogel
Compound 3A-ANT I (+/-)-(3-R/S,4-S/R,5-Z,7-R/S)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE
![(+/-)-(3-R/S,4-S/R,5-Z,7-R/S)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE](/api/compound/O8pLPr0ueZ.png?h=300&w=458 "(+/-)-(3-R/S,4-S/R,5-Z,7-R/S)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE")
Compound 3A-SYN (+/-)-(3-R/S,4-R/S,5-Z,7-S/R)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE
![(+/-)-(3-R/S,4-R/S,5-Z,7-S/R)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE](/api/compound/EHpaB0HeliC.png?h=300&w=458 "(+/-)-(3-R/S,4-R/S,5-Z,7-S/R)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE")
Compound 3C (+/-)-(3-R/S,5-Z)-4-BENZYLOXY-7-(METHYLSULFONYL)-2,4-DIMETHYLOCT-5-EN-2-ONE;MIXTURE-OF-SYN-AND-ANTI-3C
Compound 4A-ANT I (+/-)-(3-R/S,4-S/R,5-E,7-S/R)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE
![(+/-)-(3-R/S,4-S/R,5-E,7-S/R)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE](/api/compound/GQSPt72ulhL.png?h=300&w=458 "(+/-)-(3-R/S,4-S/R,5-E,7-S/R)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE")
Compound 4A-SYN (+/-)-(3-R/S,4-R/S,5-E,7-R/S)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE
![(+/-)-(3-R/S,4-R/S,5-E,7-R/S)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE](/api/compound/5jG1js0idLE.png?h=300&w=458 "(+/-)-(3-R/S,4-R/S,5-E,7-R/S)-4-HYDROXY-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCT-5-EN-2-ONE")
Compound 5A (3-E,5-E)-7-(BUTYLSULFONYL)-3-METHYLHEPT-3,5-DIEN-2-ONE
Compound 5B (+/-)-(4-E,6-E,8-R/S)-3,5-DIMETHYL-8-[(2,4-DINITROPHENYL)-SULFONYL]-NONA-4,6-DIEN-3-ONE
![(+/-)-(4-E,6-E,8-R/S)-3,5-DIMETHYL-8-[(2,4-DINITROPHENYL)-SULFONYL]-NONA-4,6-DIEN-3-ONE](/api/compound/N2Eie2uHo3.png?h=300&w=458 "(+/-)-(4-E,6-E,8-R/S)-3,5-DIMETHYL-8-[(2,4-DINITROPHENYL)-SULFONYL]-NONA-4,6-DIEN-3-ONE")
Compound 5C (+/-)-(3-E,5-E,7-R/S)-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCTA-3,5-DIEN-2-ONE
![(+/-)-(3-E,5-E,7-R/S)-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCTA-3,5-DIEN-2-ONE](/api/compound/30o3oEdaiz3.png?h=300&w=458 "(+/-)-(3-E,5-E,7-R/S)-3,5-DIMETHYL-7-[(METHYL)-SULFONYL]-OCTA-3,5-DIEN-2-ONE")
Compound 6B (+/-)-(3-E,5-Z,7-R/S)-3,5-DIMETHYL-7-[(2-METHYLPROP-2-ENYL)-SULFONYL]-OCTA-3,5-DIEN-2-ONE
![(+/-)-(3-E,5-Z,7-R/S)-3,5-DIMETHYL-7-[(2-METHYLPROP-2-ENYL)-SULFONYL]-OCTA-3,5-DIEN-2-ONE](/api/compound/HrEScYF5Rfn.png?h=300&w=458 "(+/-)-(3-E,5-Z,7-R/S)-3,5-DIMETHYL-7-[(2-METHYLPROP-2-ENYL)-SULFONYL]-OCTA-3,5-DIEN-2-ONE")
Compound 6C (+/-)-(2-E,4-E,6-R/S)-4-METHYL-6-[(2,4-DINITROPHENYL)-SULFONYL]-PHENYLHEPTA-2,4-DIEN-1-ONE
![(+/-)-(2-E,4-E,6-R/S)-4-METHYL-6-[(2,4-DINITROPHENYL)-SULFONYL]-PHENYLHEPTA-2,4-DIEN-1-ONE](/api/compound/33guHEAvv65.png?h=300&w=458 "(+/-)-(2-E,4-E,6-R/S)-4-METHYL-6-[(2,4-DINITROPHENYL)-SULFONYL]-PHENYLHEPTA-2,4-DIEN-1-ONE")
Compound 8 (+/-)-(2-R/S,4-Z)-3-HYDROXY-2,4-DIMETHYL-6-[(METHYL)-SULFONYL]-1-PHENYLHEPT-4-EN-1-ONE;MIXTURE-OF-SYN-AND-ANTI
![(+/-)-(2-R/S,4-Z)-3-HYDROXY-2,4-DIMETHYL-6-[(METHYL)-SULFONYL]-1-PHENYLHEPT-4-EN-1-ONE;MIXTURE-OF-SYN-AND-ANTI](/api/compound/7Zktou1OYSf.png?h=300&w=458 "(+/-)-(2-R/S,4-Z)-3-HYDROXY-2,4-DIMETHYL-6-[(METHYL)-SULFONYL]-1-PHENYLHEPT-4-EN-1-ONE;MIXTURE-OF-SYN-AND-ANTI")
Compound 9-ANTI (+/-)-(2-R/S,3-R/S,4-E,6-S/R)-3-[[(TERT.-BUTYL)-DIMETHYLSILYL]-OXY]-6-(METHYLSULFONYL)-2,4-DIMETHYL-1-(2,4,6-TRIMETHOXYPHENYL)-HEPT-4-EN-1-ONE
![(+/-)-(2-R/S,3-R/S,4-E,6-S/R)-3-[[(TERT.-BUTYL)-DIMETHYLSILYL]-OXY]-6-(METHYLSULFONYL)-2,4-DIMETHYL-1-(2,4,6-TRIMETHOXYPHENYL)-HEPT-4-EN-1-ONE](/api/compound/BRzoxnDSZr5.png?h=300&w=458 "(+/-)-(2-R/S,3-R/S,4-E,6-S/R)-3-[[(TERT.-BUTYL)-DIMETHYLSILYL]-OXY]-6-(METHYLSULFONYL)-2,4-DIMETHYL-1-(2,4,6-TRIMETHOXYPHENYL)-HEPT-4-EN-1-ONE")
Compound 9-SYN (+/-)-(2-R/S,3-R/S,4-E,6-R/S)-3-[[(TERT.-BUTYL)-DIMETHYLSILYL]-OXY]-6-(METHYLSULFONYL)-2,4-DIMETHYL-1-(2,4,6-TRIMETHOXYPHENYL)-HEPT-4-EN-1-ONE
![(+/-)-(2-R/S,3-R/S,4-E,6-R/S)-3-[[(TERT.-BUTYL)-DIMETHYLSILYL]-OXY]-6-(METHYLSULFONYL)-2,4-DIMETHYL-1-(2,4,6-TRIMETHOXYPHENYL)-HEPT-4-EN-1-ONE](/api/compound/FoqRqMznKI9.png?h=300&w=458 "(+/-)-(2-R/S,3-R/S,4-E,6-R/S)-3-[[(TERT.-BUTYL)-DIMETHYLSILYL]-OXY]-6-(METHYLSULFONYL)-2,4-DIMETHYL-1-(2,4,6-TRIMETHOXYPHENYL)-HEPT-4-EN-1-ONE")
Compound 12 (+/-)-(5-R/S,6-Z,8-S/R)-8-(ETHYLSULFONYL)-5-HYDROXY-2,2,6-TRIMETHYLNON-6-EN-3-ONE
Compound 13 (+/-)-(5-R/S,6-Z,8-S/R)-5-(BENZYLOXY)-8-(BUTYLSULFONYL)-2,2,6-TRIMETHYLNON-6-EN-3-ONE
Compound 14 (+/-)-(4-R/S,6-Z)-5-HYDROXY-8-(2-METHYLPROPANE-1-SULFONYL)-4,6-DIMETHYLNON-6-EN-3-ONE;MIXTURE-OF-SYN-AND-ANTI
Compound 15 (+/-)-(3-R/S,5-Z)-4-(BENZYLOXY)-3,5-DIMETHYL-7-(2-METHYL-PROP-1-YLSULFONYL)-OCT-5-EN-2-ONE;MIXTURE-OF-SYN-AND-ANTI
Compound 16 (+/-)-(3-R/S,4-Z,6-S/R)-6-[(2,4-DINITROPHENYL)-SULFONYL]-3-HYDROXY-4-METHYL-1-PHENYLHEPT-4-EN-1-ONE
![(+/-)-(3-R/S,4-Z,6-S/R)-6-[(2,4-DINITROPHENYL)-SULFONYL]-3-HYDROXY-4-METHYL-1-PHENYLHEPT-4-EN-1-ONE](/api/compound/86TNYdraHbs.png?h=300&w=458 "(+/-)-(3-R/S,4-Z,6-S/R)-6-[(2,4-DINITROPHENYL)-SULFONYL]-3-HYDROXY-4-METHYL-1-PHENYLHEPT-4-EN-1-ONE")
Compound 17 (+/-)-(5-R/S,6-Z,8-S/R)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-2,2,6-TRIMETHYLNON-6-EN-3-ONE
![(+/-)-(5-R/S,6-Z,8-S/R)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-2,2,6-TRIMETHYLNON-6-EN-3-ONE](/api/compound/5D3v5zR5CM7.png?h=300&w=458 "(+/-)-(5-R/S,6-Z,8-S/R)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-2,2,6-TRIMETHYLNON-6-EN-3-ONE")
Compound 18-ANTI (+/-)-(4-R/S,5-S/R,6-E,8-S/R)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-4,6-DIMETHYLNON-6-EN-3-ONE
![(+/-)-(4-R/S,5-S/R,6-E,8-S/R)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-4,6-DIMETHYLNON-6-EN-3-ONE](/api/compound/KzuLQnvpWtB.png?h=300&w=458 "(+/-)-(4-R/S,5-S/R,6-E,8-S/R)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-4,6-DIMETHYLNON-6-EN-3-ONE")
Compound 18-SYN (+/-)-(4-R/S,5-R/S,6-E,8-R/S)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-4,6-DIMETHYLNON-6-EN-3-ONE
![(+/-)-(4-R/S,5-R/S,6-E,8-R/S)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-4,6-DIMETHYLNON-6-EN-3-ONE](/api/compound/5xRznWq5xLq.png?h=300&w=458 "(+/-)-(4-R/S,5-R/S,6-E,8-R/S)-8-[(2,4-DINITROPHENYL)-SULFONYL]-5-HYDROXY-4,6-DIMETHYLNON-6-EN-3-ONE")
Compound 19-ANTI (+/-)-(2-S/R)-2-[(1-R/S,2-E)-1-HYDROXY-2-METHYL-4-[(2,4-DINITROPHENYL)-SULFONYL]-PENT-2-ENYL]-CYCLOHEXANONE
![(+/-)-(2-S/R)-2-[(1-R/S,2-E)-1-HYDROXY-2-METHYL-4-[(2,4-DINITROPHENYL)-SULFONYL]-PENT-2-ENYL]-CYCLOHEXANONE](/api/compound/1ZnZCMPeB50.png?h=300&w=458 "(+/-)-(2-S/R)-2-[(1-R/S,2-E)-1-HYDROXY-2-METHYL-4-[(2,4-DINITROPHENYL)-SULFONYL]-PENT-2-ENYL]-CYCLOHEXANONE")
Compound 19-SYN (+/-)-(2-R/S)-2-[(1-R/S,2-E)-1-HYDROXY-2-METHYL-4-[(2,4-DINITROPHENYL)-SULFONYL]-PENT-2-ENYL]-CYCLOHEXANONE
![(+/-)-(2-R/S)-2-[(1-R/S,2-E)-1-HYDROXY-2-METHYL-4-[(2,4-DINITROPHENYL)-SULFONYL]-PENT-2-ENYL]-CYCLOHEXANONE](/api/compound/LLPRCwLdLoY.png?h=300&w=458 "(+/-)-(2-R/S)-2-[(1-R/S,2-E)-1-HYDROXY-2-METHYL-4-[(2,4-DINITROPHENYL)-SULFONYL]-PENT-2-ENYL]-CYCLOHEXANONE")
Citation
| Citation | ORG.LETTERS,7,897(2005) |
|---|---|
| Journal | Organic Letters |
| Issue | 5 |
| Volume | 7 |
| Page(s) | 897-900 |
| Year | 2005 |
| Author(s) | Laure C. Bouchez, Cotinica Craita, Pierre Vogel |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ol050006z |