Spectra for:
Pierre Van de Weghe, Darina Aoun, Jean-Guy Boiteau, Jacques Eustache
Compound 1 (Z,1S)-1-[(2S,5S,7R,8R)-2-[(2S)-2-hydroxyhept-6-enyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]hex-3-ene-1,6-diol
![(Z,1S)-1-[(2S,5S,7R,8R)-2-[(2S)-2-hydroxyhept-6-enyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]hex-3-ene-1,6-diol](/api/compound/B4aKdsPVgwh.png?h=300&w=458 "(Z,1S)-1-[(2S,5S,7R,8R)-2-[(2S)-2-hydroxyhept-6-enyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]hex-3-ene-1,6-diol")
Compound 4 (6S,8S)-trideca-1,12-diene-6,8-diol
Compound 7A (2R,6S)-2-(iodomethyl)-6-[(2S)-2-(4-methoxybenzyl)oxyhept-6-enyl]tetrahydropyran
![(2R,6S)-2-(iodomethyl)-6-[(2S)-2-(4-methoxybenzyl)oxyhept-6-enyl]tetrahydropyran](/api/compound/CpReNzPwcIj.png?h=300&w=458 "(2R,6S)-2-(iodomethyl)-6-[(2S)-2-(4-methoxybenzyl)oxyhept-6-enyl]tetrahydropyran")
Compound 7B (2S,6S)-2-(iodomethyl)-6-[(2S)-2-(4-methoxybenzyl)oxyhept-6-enyl]tetrahydropyran
![(2S,6S)-2-(iodomethyl)-6-[(2S)-2-(4-methoxybenzyl)oxyhept-6-enyl]tetrahydropyran](/api/compound/JXhsuTSQbD0.png?h=300&w=458 "(2S,6S)-2-(iodomethyl)-6-[(2S)-2-(4-methoxybenzyl)oxyhept-6-enyl]tetrahydropyran")
Compound 8A (6S)-7-[(2S,6R)-6-(iodomethyl)tetrahydropyran-2-yl]-6-(4-methoxybenzyl)oxy-hept-1-en-3-ol
![(6S)-7-[(2S,6R)-6-(iodomethyl)tetrahydropyran-2-yl]-6-(4-methoxybenzyl)oxy-hept-1-en-3-ol](/api/compound/1RcyD8g6SMk.png?h=300&w=458 "(6S)-7-[(2S,6R)-6-(iodomethyl)tetrahydropyran-2-yl]-6-(4-methoxybenzyl)oxy-hept-1-en-3-ol")
Compound 11 (Z,2R,3R,6S,9S)-1-(tert-butyl-di(phenyl)silyl)oxy-10-[(2S,6R)-6-(iodomethyl)tetrahydropyran-2-yl]-9-(4-methoxybenzyl)oxy-3-methyl-dec-4-ene-2,6-diol
![(Z,2R,3R,6S,9S)-1-(tert-butyl-di(phenyl)silyl)oxy-10-[(2S,6R)-6-(iodomethyl)tetrahydropyran-2-yl]-9-(4-methoxybenzyl)oxy-3-methyl-dec-4-ene-2,6-diol](/api/compound/H7dzHVTyiNI.png?h=300&w=458 "(Z,2R,3R,6S,9S)-1-(tert-butyl-di(phenyl)silyl)oxy-10-[(2S,6R)-6-(iodomethyl)tetrahydropyran-2-yl]-9-(4-methoxybenzyl)oxy-3-methyl-dec-4-ene-2,6-diol")
Compound 12 tert-butyl-[[(2S,5S,7R,8R)-2-[[(2S,6R)-6-(iodomethyl)oxan-2-yl]methyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]methoxy]-di(phenyl)silane
![tert-butyl-[[(2S,5S,7R,8R)-2-[[(2S,6R)-6-(iodomethyl)oxan-2-yl]methyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]methoxy]-di(phenyl)silane](/api/compound/58bHUWRO6Xp.png?h=300&w=458 "tert-butyl-[[(2S,5S,7R,8R)-2-[[(2S,6R)-6-(iodomethyl)oxan-2-yl]methyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]methoxy]-di(phenyl)silane")
Compound 13 [(2S,5S,7R,8R)-2-[[(2S,6R)-6-(iodomethyl)oxan-2-yl]methyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]methanol
![[(2S,5S,7R,8R)-2-[[(2S,6R)-6-(iodomethyl)oxan-2-yl]methyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]methanol](/api/compound/4sUMVCbmq2C.png?h=300&w=458 "[(2S,5S,7R,8R)-2-[[(2S,6R)-6-(iodomethyl)oxan-2-yl]methyl]-8-methyl-1,6-dioxaspiro[4.5]decan-7-yl]methanol")
Compound 15 16R-ISOMER
Compound 15 16S-ISOMER
Compound 16 (2S)-1-[(2S,5S,7R,8R)-7-[(Z,1R)-1-hydroxy-6-(4-methoxybenzyl)oxy-hex-3-enyl]-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl]hept-6-en-2-ol
![(2S)-1-[(2S,5S,7R,8R)-7-[(Z,1R)-1-hydroxy-6-(4-methoxybenzyl)oxy-hex-3-enyl]-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl]hept-6-en-2-ol](/api/compound/B3frNlqa1E3.png?h=300&w=458 "(2S)-1-[(2S,5S,7R,8R)-7-[(Z,1R)-1-hydroxy-6-(4-methoxybenzyl)oxy-hex-3-enyl]-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl]hept-6-en-2-ol")
Compound 18 tributyl-[(E)-5-(4-methoxybenzyl)oxypent-2-enyl]stannane
![tributyl-[(E)-5-(4-methoxybenzyl)oxypent-2-enyl]stannane](/api/compound/2SATW5DaOY2.png?h=300&w=458 "tributyl-[(E)-5-(4-methoxybenzyl)oxypent-2-enyl]stannane")
Citation
| Citation | ORG.LETTERS,4,4105(2002) |
|---|---|
| Journal | Organic Letters |
| Issue | 23 |
| Volume | 4 |
| Page(s) | 4105-4108 |
| Year | 2002 |
| Author(s) | Pierre Van de Weghe, Darina Aoun, Jean-Guy Boiteau, Jacques Eustache |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ol0268438 |