Spectra for:
A. F. Barrero, E. J. Alvarez-Manzaneda, R. Alvarez-Manzaneda, R. Chahboun, R. Meneses, J. M. Cuerva, M. Aparicio, J. L. Romera
Compound 22A (4S,5S,7R,8R,9R,10S,16R)-4-BETA,20-DI-(ACETOXYMETHYL)-13,16-BETA-DI-(PHENYLTHIO)-21-NORPICRAS-13-ENE
Compound 22B (4S,5S,7R,8R,9R,10S,16R)-4-BETA,20-DI-(ACETOXYMETHYL)-13,16-ALPHA-DI-(PHENYLTHIO)-21-NORPICRAS-13-ENE
#10;(1'R,3'R,4A'S,5'S,8A'S)-4-[3',4',4A',5',6',7',8',8A'-OCTAHYDRO-2'-(1'H)-METHYLENE-3'-ALPHA-HYDROXY-5'-BETA-METHOXYCARBONYL-5'-ALPHA,8A'-BETA-DIMETHYLNAPHTH
#11;(1'R,3'R,4A'S,5'S,8A'S)-4-[3'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY-3',4',4A',5',6',7',8',8A'-OCTAHYDRO-2'-(1'H)-METHYLENE-5'-BETA-METHOXYCARBONYL-5'-ALPHA,
#12;(1'R,3'R,4A'S,5'S,8A'S,2R/S)-6-[3'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY-3',4',4A',5',6',7',8',8A'-OCTAHYDRO-2'-(1'H)-METHYLENE-5'-BETA-METHOXYCARBONYL-5'-A
#13;(1'R,3'R,4A'S,5'S,8A'S,2R/S)-6-[3'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY-3',4',4A',5',6',7',8',8A'-OCTAHYDRO-2'-(1'H)-METHYLENE-5'-BETA-METHOXYCARBONYL-5'-A
#14;(1'R,3'R,4A'S,5'S,8A'S)-6-[3'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY-3',4',4A',5',6',7',8',8A'-OCTAHYDRO-2'-(1'H)-METHYLENE-5'-BETA-METHOXYCARBONYL-5'-ALPHA,
#15;(1'R,3'R,4A'S,5'S,8A'S)-6-[3'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY-3',4',4A',5',6',7',8',8A'-OCTAHYDRO-2'-(1'H)-METHYLENE-5'-BETA-METHOXYCARBONYL-5'-ALPHA,
#16;(1'R,3'R,4A'S,5'S,8A'S)-6-[3'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY-3',4',4A',5',6',7',8',8A'-OCTAHYDRO-5'-BETA-METHOXYCARBONYL-5'-ALPHA,8A'-BETA-DIMETHYL-2
#17;(1S,4AS,4BR,9R,10AS)-[9'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,4A,4B,5,6,7,9,10,10A-DODECAHYDRO-1-BETA-METHOXYCARBONYL-8-(2',2'-DIMETHOXYETHYL)-1-A
![#17;(1S,4AS,4BR,9R,10AS)-[9'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,4A,4B,5,6,7,9,10,10A-DODECAHYDRO-1-BETA-METHOXYCARBONYL-8-(2',2'-DIMETHOXYETHYL)-1-A](/api/compound/Lp7dpWBrJd3.png?h=300&w=458 "#17;(1S,4AS,4BR,9R,10AS)-[9'-ALPHA-(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,4A,4B,5,6,7,9,10,10A-DODECAHYDRO-1-BETA-METHOXYCARBONYL-8-(2',2'-DIMETHOXYETHYL)-1-A")
#18A;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-8-BETA-CYANO-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-4-BETA-METHOXYCARBONYL-16-B
![#18A;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-8-BETA-CYANO-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-4-BETA-METHOXYCARBONYL-16-B](/api/compound/20wKtXAYxWA.png?h=300&w=458 "#18A;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-8-BETA-CYANO-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-4-BETA-METHOXYCARBONYL-16-B")
#18B;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-8-BETA-CYANO-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-4-BETA-METHOXYCARBONYL-16-A
![#18B;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-8-BETA-CYANO-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-4-BETA-METHOXYCARBONYL-16-A](/api/compound/H2BiN8YYAsO.png?h=300&w=458 "#18B;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-8-BETA-CYANO-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-4-BETA-METHOXYCARBONYL-16-A")
#20;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-16-BETA-METHOXY-17-OXA-CYCLOPENTA-[A]-4-B
![#20;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-16-BETA-METHOXY-17-OXA-CYCLOPENTA-[A]-4-B](/api/compound/3jiAHA4THD2.png?h=300&w=458 "#20;(4S,5S,7R,8R,9R,10S,16R)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-16-BETA-METHOXY-17-OXA-CYCLOPENTA-[A]-4-B")
#21;(4S,5S,7R,8R,9R,10S,16R)-4-BETA,8-BETA-DI-(ACETOXYMETHYL)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-16-BETA-
![#21;(4S,5S,7R,8R,9R,10S,16R)-4-BETA,8-BETA-DI-(ACETOXYMETHYL)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-16-BETA-](/api/compound/G2ep7bXl4N9.png?h=300&w=458 "#21;(4S,5S,7R,8R,9R,10S,16R)-4-BETA,8-BETA-DI-(ACETOXYMETHYL)-7-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,2,3,4,5,6,7,8,9,10,11,12,15,16-TETRADECAHYDRO-16-BETA-")
Citation
| Citation | ORG.LETTERS,3,647(2001) |
|---|---|
| Journal | Organic Letters |
| Issue | 5 |
| Volume | 3 |
| Page(s) | 647-650 |
| Year | 2001 |
| Author(s) | A. F. Barrero, E. J. Alvarez-Manzaneda, R. Alvarez-Manzaneda, R. Chahboun, R. Meneses, J. M. Cuerva, M. Aparicio, J. L. Romera |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ol0065322 |