Spectra for:
Scott E. Denmark, Donald S. Middleton
Compound 1 Methyl (E)-7-nitro-2,7-octadienoate
Compound 2-(E) METHYL-(E)-8-NITRO-2,8-NONADIENOATE
Compound 2-(Z) METHYL-(Z)-8-NITRO-2,8-NONADIENOATE
Compound 16 METHYL-(2R*,2AR*,5AR*)-8-BUTOXYOCTAHYDRO-1,9-DIOXA-9A-AZACYCLOPENT-[C]-INDENE-2-CARBOXYLATE
![METHYL-(2R*,2AR*,5AR*)-8-BUTOXYOCTAHYDRO-1,9-DIOXA-9A-AZACYCLOPENT-[C]-INDENE-2-CARBOXYLATE](/api/compound/40QPqL5qXua.png?h=300&w=458 "METHYL-(2R*,2AR*,5AR*)-8-BUTOXYOCTAHYDRO-1,9-DIOXA-9A-AZACYCLOPENT-[C]-INDENE-2-CARBOXYLATE")
Compound 20 Methyl (2R*,2aR*,6aR*)-9-Butoxyoctahydro-1,10-dioxa-10a-azacyclohex[c]indene-2-carboxylate
![Methyl (2R*,2aR*,6aR*)-9-Butoxyoctahydro-1,10-dioxa-10a-azacyclohex[c]indene-2-carboxylate](/api/compound/BlMvyrvFiVh.png?h=300&w=458 "Methyl (2R*,2aR*,6aR*)-9-Butoxyoctahydro-1,10-dioxa-10a-azacyclohex[c]indene-2-carboxylate")
Compound 22 METHYL-(2R*,2AS*,6AS*)-9-BUTOXYOCTAHYDRO-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE;MINOR-DIASTEREOMER
![METHYL-(2R*,2AS*,6AS*)-9-BUTOXYOCTAHYDRO-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE;MINOR-DIASTEREOMER](/api/compound/GtegbqSbjMc.png?h=300&w=458 "METHYL-(2R*,2AS*,6AS*)-9-BUTOXYOCTAHYDRO-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE;MINOR-DIASTEREOMER")
Compound 22 METHYL-(2R*,2AS*,6AS*)-9-BUTOXYOCTAHYDRO-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE;MAJOR-DIASTEREOMER
![METHYL-(2R*,2AS*,6AS*)-9-BUTOXYOCTAHYDRO-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE;MAJOR-DIASTEREOMER](/api/compound/8dxeXLY9DyW.png?h=300&w=458 "METHYL-(2R*,2AS*,6AS*)-9-BUTOXYOCTAHYDRO-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE;MAJOR-DIASTEREOMER")
Compound 23 (1R*,6AR*,9AR*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOPENTA-[H]-PYRROLIZINE-2-ONE
![(1R*,6AR*,9AR*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOPENTA-[H]-PYRROLIZINE-2-ONE](/api/compound/CeJhBIlv6nT.png?h=300&w=458 "(1R*,6AR*,9AR*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOPENTA-[H]-PYRROLIZINE-2-ONE")
Compound 24 (1R*,6AR*,10AR*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE
![(1R*,6AR*,10AR*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE](/api/compound/65rrq8hA1v3.png?h=300&w=458 "(1R*,6AR*,10AR*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE")
Compound 25 (1R*,6AS*,10AS*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE
![(1R*,6AS*,10AS*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE](/api/compound/6qWtC6AuyN5.png?h=300&w=458 "(1R*,6AS*,10AS*)-OCTAHYDRO-1-HYDROXY-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE")
Compound 26 (1S*,6AR*,10AR*)-OCTAHYDRO-1-O-(IMIDAZOYLTHIOCARBONYL)-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE
![(1S*,6AR*,10AR*)-OCTAHYDRO-1-O-(IMIDAZOYLTHIOCARBONYL)-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE](/api/compound/9vMFmBkD4mg.png?h=300&w=458 "(1S*,6AR*,10AR*)-OCTAHYDRO-1-O-(IMIDAZOYLTHIOCARBONYL)-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE")
Compound 27 (1R*,6AR*,10AR*)-OCTAHYDRO-1-O-(IMIDAZOYLTHIOCARBONYL)-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE
![(1R*,6AR*,10AR*)-OCTAHYDRO-1-O-(IMIDAZOYLTHIOCARBONYL)-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE](/api/compound/FEg4sbDAITL.png?h=300&w=458 "(1R*,6AR*,10AR*)-OCTAHYDRO-1-O-(IMIDAZOYLTHIOCARBONYL)-2H-CYCLOHEXA-[H]-PYRROLIZINE-2-ONE")
Compound 31 METHYL-(2S,2AS,5AS,8S)-8-[(1R,2S)-2-PHENYLCYCLOHEXYLOXY]-1,9-DIOXA-9A-AZACYCLOPENT-[C]-INDENE-2-CARBOXYLATE
![METHYL-(2S,2AS,5AS,8S)-8-[(1R,2S)-2-PHENYLCYCLOHEXYLOXY]-1,9-DIOXA-9A-AZACYCLOPENT-[C]-INDENE-2-CARBOXYLATE](/api/compound/BWne0rkIPGK.png?h=300&w=458 "METHYL-(2S,2AS,5AS,8S)-8-[(1R,2S)-2-PHENYLCYCLOHEXYLOXY]-1,9-DIOXA-9A-AZACYCLOPENT-[C]-INDENE-2-CARBOXYLATE")
Compound 32 (1R*,6AR*,9AR*)-3,5-DINITRO-N-[(OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL)-OXY]-BENZAMIDE
![(1R*,6AR*,9AR*)-3,5-DINITRO-N-[(OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL)-OXY]-BENZAMIDE](/api/compound/5B3lJz5ZNsR.png?h=300&w=458 "(1R*,6AR*,9AR*)-3,5-DINITRO-N-[(OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL)-OXY]-BENZAMIDE")
Compound 33 METHYL-(2S,2AS,6AS,9S)-9-[(1R,2S)-2-PHENYLCYCLOHEXYLOXY]-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE
![METHYL-(2S,2AS,6AS,9S)-9-[(1R,2S)-2-PHENYLCYCLOHEXYLOXY]-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE](/api/compound/DGORrItU54D.png?h=300&w=458 "METHYL-(2S,2AS,6AS,9S)-9-[(1R,2S)-2-PHENYLCYCLOHEXYLOXY]-1,10-DIOXA-10A-AZACYCLOHEX-[C]-INDENE-2-CARBOXYLATE")
Compound 34 (1R*,6AR*,10AR*)-3,5-DINITRO-N-[(OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL)-OXY]-BENZAMIDE
![(1R*,6AR*,10AR*)-3,5-DINITRO-N-[(OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL)-OXY]-BENZAMIDE](/api/compound/A52VSFGWjlS.png?h=300&w=458 "(1R*,6AR*,10AR*)-3,5-DINITRO-N-[(OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL)-OXY]-BENZAMIDE")
Compound 35A (1S,6AS,9AS)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER
![(1S,6AS,9AS)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER](/api/compound/KIhJaxlXrNR.png?h=300&w=458 "(1S,6AS,9AS)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER")
Compound 35B (1R,6AR,9AR)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER
![(1R,6AR,9AR)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER](/api/compound/eimMxAyQp4.png?h=300&w=458 "(1R,6AR,9AR)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOPENTA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER")
Compound 36A (1S,6AS,10S)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER
![(1S,6AS,10S)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER](/api/compound/KBeRXM4wCAB.png?h=300&w=458 "(1S,6AS,10S)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER")
Compound 36B (1R,6AR,10R)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER
![(1R,6AR,10R)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER](/api/compound/KmvISdQIZKI.png?h=300&w=458 "(1R,6AR,10R)-ALPHA-METHOXY-OCTAHYDRO-2-OXO-2-H-CYCLOHEXA-[H]-PYRROLIZIN-1-YL-BENZENE-ACETIC-ACIDESTER")
Citation
| Citation | J.ORG.CHEM.,63,1604(1998) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| Issue | 5 |
| Volume | 63 |
| Page(s) | 1604-1618 |
| Year | 1998 |
| Author(s) | Scott E. Denmark, Donald S. Middleton |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/jo9719057 |