Spectra for:
Edelmiro Momán, Daniel Nicoletti, Antonio Mouriño
Compound 2A 20-(17->18)-ABEO-1-ALPHA,25-DIHYDROXY-21-NORVITAMIN-D3
Compound 2B 20-(17->18)-ABEO-1-ALPHA,25-DIHYDROXY-22-HOMO-21-NORVITAMIN-D3
Compound 2C 20-(17->18)-ABEO-1-ALPHA,25-DIHYDROXY-22,23-DIHOMO-21-NORVITAMIN-D3
Compound 3A 20-(17->18)-ABEO-DE-A,B-25-HYDROXY-21-NORCHOLESTAN-8-ONE
Compound 3B 20-(17->18)-ABEO-DE-A,B-25-HYDROXY-22-HOMO-21-NORCHOLESTAN-8-ONE
Compound 3C 20-(17->18)-ABEO-DE-A,B-25-HYDROXY-22,23-DIHOMO-21-NORCHOLESTAN-8-ONE
Compound 5 DE-A,B-ANDROSTAN-8-BETA-OL
Compound 11 8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-BETA-YL-ACETATE
![8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-BETA-YL-ACETATE](/api/compound/qkdjhnE8Ju.png?h=300&w=458 "8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-BETA-YL-ACETATE")
Compound 12 8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-BETA-OL
![8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-BETA-OL](/api/compound/9CE2RVU42ds.png?h=300&w=458 "8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-BETA-OL")
Compound 13 8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-ONE
![8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-ONE](/api/compound/2SJrNaaCkrS.png?h=300&w=458 "8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-ONE")
Compound 14 8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROST-16-ENE-17-YL-TRIFLUOROMETHANESULFONATE
![8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROST-16-ENE-17-YL-TRIFLUOROMETHANESULFONATE](/api/compound/CudoPQJVhzR.png?h=300&w=458 "8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROST-16-ENE-17-YL-TRIFLUOROMETHANESULFONATE")
Compound 15 DE-A,B-(8-BETA)-8,18-EPOXYANDROSTANE
Compound 16 DE-A,B-8-BETA-HYDROXY-ANDROSTAN-18-OIC-ACID-LACTONE
Compound 21B (5-Carboxypentyl)triphenylphosphonium bromide
Compound 28 DE-A,B-8-ALPHA,18-DIACETOXY-ANDROSTANE
Compound 29 DE-A,B-8-ALPHA,18-DIHYDROXY-ANDROSTANE
Compound 30 DE-A,B-8-ALPHA-HYDROXY-ANDROSTAN-18-AL
Compound 31 8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-18-AL
![8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-18-AL](/api/compound/Damr61VcOoC.png?h=300&w=458 "8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-18-AL")
Compound 37 ETHYL-(18E)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGN-18-EN-21-ATE
![ETHYL-(18E)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGN-18-EN-21-ATE](/api/compound/LjFGkLEzrXG.png?h=300&w=458 "ETHYL-(18E)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGN-18-EN-21-ATE")
Compound 38 ETHYL-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGNAN-21-ATE
![ETHYL-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGNAN-21-ATE](/api/compound/4cHcazOUUW.png?h=300&w=458 "ETHYL-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGNAN-21-ATE")
Compound 39 20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGNAN-21-AL
![20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGNAN-21-AL](/api/compound/6uwWb2qLZbe.png?h=300&w=458 "20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGNAN-21-AL")
Compound 40A (18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-21-NORCHOL-18-ENE
![(18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-21-NORCHOL-18-ENE](/api/compound/A1ghoqHTvIV.png?h=300&w=458 "(18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-21-NORCHOL-18-ENE")
Compound 40B (18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-22-HOMO-21-NORCHOL-18-ENE
![(18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-22-HOMO-21-NORCHOL-18-ENE](/api/compound/7NtpVK02kF5.png?h=300&w=458 "(18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-22-HOMO-21-NORCHOL-18-ENE")
Compound 40C (22Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-22,23-DIHOMO-21-NORCHOL-22-ENE
![(22Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-22,23-DIHOMO-21-NORCHOL-22-ENE](/api/compound/G6lX9g8KVvZ.png?h=300&w=458 "(22Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-CARBOXYDE-A,B-22,23-DIHOMO-21-NORCHOL-22-ENE")
Compound 41A (18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-21-NORCHOLEST-18-EN-25-OL
![(18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-21-NORCHOLEST-18-EN-25-OL](/api/compound/2cgPqR21Sy0.png?h=300&w=458 "(18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-21-NORCHOLEST-18-EN-25-OL")
Compound 41B (18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-22-HOMO-21-NORCHOLEST-18-EN-25-OL
![(18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-22-HOMO-21-NORCHOLEST-18-EN-25-OL](/api/compound/Ivc9tNMRh87.png?h=300&w=458 "(18Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-22-HOMO-21-NORCHOLEST-18-EN-25-OL")
Compound 41C (22Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-22,23-DIHOMO-21-NORCHOLEST-22-EN-25-OL
![(22Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-22,23-DIHOMO-21-NORCHOLEST-22-EN-25-OL](/api/compound/J6h7gIleDk2.png?h=300&w=458 "(22Z)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-22,23-DIHOMO-21-NORCHOLEST-22-EN-25-OL")
Compound 42A (18Z)-20-(17->18)-ABEO-DE-A,B-8-ALPHA,25-DIHYDROXY-21-NORCHOLEST-18-ENE
Compound 42B (18Z)-20-(17->18)-ABEO-DE-A,B-8-ALPHA,25-DIHYDROXY-22-HOMO-21-NORCHOLEST-18-ENE
Compound 42C (22Z)-20-(17->18)-ABEO-DE-A,B-8-ALPHA,25-DIHYDROXY-22,23-DIHOMO-21-NORCHOLEST-22-ENE
Compound 43A 20-(17->18)-ABEO-DE-A,B-8-ALPHA,25-DIHYDROXY-21-NORCHOLESTANE
Compound 43B 20-(17->18)-ABEO-DE-A,B-8-ALPHA,25-DIHYDROXY-22-HOMO-21-NORCHOLESTANE
Compound 43C 20-(17->18)-ABEO-DE-A,B-8-ALPHA,25-DIHYDROXY-22,23-DIHOMO-21-NORCHOLESTANE
Compound 44A 20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-21-NORVITAMIN-D3
![20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-21-NORVITAMIN-D3](/api/compound/3JS8xSmvzVu.png?h=300&w=458 "20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-21-NORVITAMIN-D3")
Compound 44B 20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-22-HOMO-21-NORVITAMIN-D3
![20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-22-HOMO-21-NORVITAMIN-D3](/api/compound/DQUvDVxm3i5.png?h=300&w=458 "20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-22-HOMO-21-NORVITAMIN-D3")
Compound 44C 20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-22,23-DIHOMO-21-NORVITAMIN-D3
![20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-22,23-DIHOMO-21-NORVITAMIN-D3](/api/compound/LKqOyW1JKB7.png?h=300&w=458 "20-(17->18)-ABEO-3-(TERT.-BUTYLDIMETHYLSILYL)-1-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-25-HYDROXY-22,23-DIHOMO-21-NORVITAMIN-D3")
Citation
| Citation | J.ORG.CHEM.,69,4615(2004) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| Issue | 14 |
| Volume | 69 |
| Page(s) | 4615-4625 |
| Year | 2004 |
| Author(s) | Edelmiro Momán, Daniel Nicoletti, Antonio Mouriño |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/jo0498664 |