Spectra for:
Santos Fustero, Belén Pina, Esther Salavert, Antonio Navarro, M. Carmen Ramírez de Arellano, Antonio Simón Fuentes
Compound (+/-)-6A (+/-)-ISOPROPYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-BUTANOATE
Compound (2R,3R,R*)-6Q (2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-BUTANOATE;MAJOR-DIASTEREOMER
Compound (2S,3S,R*)-6Q (2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-BUTANOATE;MINOR-DIASTEREOMER
Compound (3R,R*)-6M (2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-BUTANOATE;MINOR-DIASTEREOMER
Compound (3S,R*)-6M (2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-BUTANOATE;MAJOR-DIASTEREOMER
Compound (3S,R*)-6N (2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-BUTANOATE;MAJOR-DIASTEREOMER
Compound (3S,R*)-6O (2S,5S,1R)-2-[1-(4-IODOPHENYL)-1-METHYLETHYL]-5-METHYLCYCLOHEXYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-BUTANOATE;MAJOR-DIASTEREOMER
![(2S,5S,1R)-2-[1-(4-IODOPHENYL)-1-METHYLETHYL]-5-METHYLCYCLOHEXYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-BUTANOATE;MAJOR-DIASTEREOMER](/api/compound/7H7fMTFP169.png?h=300&w=458 "(2S,5S,1R)-2-[1-(4-IODOPHENYL)-1-METHYLETHYL]-5-METHYLCYCLOHEXYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-BUTANOATE;MAJOR-DIASTEREOMER")
Compound 4A ISOPROPYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE
Compound 4C ISOPROPYL-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE;(Z)-ENAMINO-TAUTOMER
Compound 4C ISOPROPYL-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE;IMINO-TAUTOMER
Compound 4D 3-[(Z)-2-CHLORO-2,2-DIFLUORO-1-(4-METHOXYANILINO)-ETHYLIDENE]-TETRAHYDRO-2-FURANONE
![3-[(Z)-2-CHLORO-2,2-DIFLUORO-1-(4-METHOXYANILINO)-ETHYLIDENE]-TETRAHYDRO-2-FURANONE](/api/compound/5gsAOUnQk30.png?h=300&w=458 "3-[(Z)-2-CHLORO-2,2-DIFLUORO-1-(4-METHOXYANILINO)-ETHYLIDENE]-TETRAHYDRO-2-FURANONE")
Compound 4E ISOPROPYL-4,4,5,5,5-PENTAFLUORO-3-(4-METHOXYANILINO)-2-PENTENOATE;(Z)-ENAMINO-TAUTOMER
Compound 4E ISOPROPYL-4,4,5,5,5-PENTAFLUORO-3-(4-METHOXYANILINO)-2-PENTENOATE;IMINO-TAUTOMER
Compound 4I (+)-ISOPROPYL-(Z)-4,4,4-TRIFLUORO-3-[(1S)-1-PHENYLETHYL-AMINO]-2-BUTENOATE
![(+)-ISOPROPYL-(Z)-4,4,4-TRIFLUORO-3-[(1S)-1-PHENYLETHYL-AMINO]-2-BUTENOATE](/api/compound/3sLJEIOVFZk.png?h=300&w=458 "(+)-ISOPROPYL-(Z)-4,4,4-TRIFLUORO-3-[(1S)-1-PHENYLETHYL-AMINO]-2-BUTENOATE")
Compound 4K (+)-(2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE
Compound 4L (+)-(2S,5S,1R)-2-[1-(4-IODOPHENYL)-1-METHYLETHYL]-5-METHYLCYCLOHEXYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE
![(+)-(2S,5S,1R)-2-[1-(4-IODOPHENYL)-1-METHYLETHYL]-5-METHYLCYCLOHEXYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE](/api/compound/8S9UD3PBKwn.png?h=300&w=458 "(+)-(2S,5S,1R)-2-[1-(4-IODOPHENYL)-1-METHYLETHYL]-5-METHYLCYCLOHEXYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE")
Compound 4M (+)-(2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-(Z)-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE;(Z)-ENAMINO-TAUTOMER
Compound 4M (+)-(2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-(Z)-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-2-BUTENOATE;IMINO-TAUTOMER
Compound 4O METHYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-2-BUTENOATE;(Z)-ENAMINO-TAUTOMER
Compound 4O METHYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-2-BUTENOATE;IMINO-TAUTOMER
Compound 4P ETHYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-ETHYL-2-BUTENOATE;IMINO-TAUTOMER
Compound 4P ETHYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-ETHYL-2-BUTENOATE;(Z)-ENAMINO-TAUTOMER
Compound 4S METHYL-(Z)-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-2-BUTENOATE;IMINO-TAUTOMER
Compound 4S METHYL-(Z)-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-2-BUTENOATE;(Z)-ENAMINO-TAUTOMER
Compound 4U (-)-(2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-(Z)-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-2-BUTENOATE;IMINO-TAUTOMER
Compound 4V (-)-(2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-2-BUTENOATE;(Z)-ENAMINO-TAUTOMER
Compound 4V (-)-(2S,5S,1R)-5-METHYL-2-(1-METHYL-1-PHENYLETHYL)-CYCLOHEXYL-(Z)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-2-BUTENOATE;IMINO-TAUTOMER
Compound 5A (+)-(Z)-[(4S)-4-BENZYL-2-OXO-1,3-OXAZOLAN-3-ILO]-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-BUTEN-1-ONA
![(+)-(Z)-[(4S)-4-BENZYL-2-OXO-1,3-OXAZOLAN-3-ILO]-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-BUTEN-1-ONA](/api/compound/BWIuq8tjngU.png?h=300&w=458 "(+)-(Z)-[(4S)-4-BENZYL-2-OXO-1,3-OXAZOLAN-3-ILO]-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-BUTEN-1-ONA")
Compound 5C (+)-(5S)-(4-METHOXYBENZYL)-5-(4-METHOXYBENZYLOXYMETHYL)-3-[(Z)-2,2,2-TRIFLUORO-1-(4-METHOXYANILINO)-ETHILIDEN]-AZOLAN-2-ONA
![(+)-(5S)-(4-METHOXYBENZYL)-5-(4-METHOXYBENZYLOXYMETHYL)-3-[(Z)-2,2,2-TRIFLUORO-1-(4-METHOXYANILINO)-ETHILIDEN]-AZOLAN-2-ONA](/api/compound/IJN7FhxLTCm.png?h=300&w=458 "(+)-(5S)-(4-METHOXYBENZYL)-5-(4-METHOXYBENZYLOXYMETHYL)-3-[(Z)-2,2,2-TRIFLUORO-1-(4-METHOXYANILINO)-ETHILIDEN]-AZOLAN-2-ONA")
Compound 6C (+/-)-ISOPROPYL-4,4,5,5,5-PENTAFLUORO-3-(4-METHOXYANILINO)-PENTANOATE
Compound 6E Isopropyl-4,4,4-trifluoro-3-[(1S)-1-phenylethylamino]-butanoate
![Isopropyl-4,4,4-trifluoro-3-[(1S)-1-phenylethylamino]-butanoate](/api/compound/Hy4wvqstm7V.png?h=300&w=458 "Isopropyl-4,4,4-trifluoro-3-[(1S)-1-phenylethylamino]-butanoate")
Compound 6F METHYL-(2S*,3R*)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYLBUTANOATE
Compound 6F (+/-)-(2R*,3R*)-METHYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYLBUTANOATE
Compound 6G (+/-)-ETHYL-(2R*,3R*)-2-ETHYL-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-BUTANOATE
Compound 6J (+/-)-METHYL-(2R*,3R*)-4-CHLORO-4,4-DIFLUORO-3-(4-METHOXYANILINO)-2-METHYL-BUTANOATE
Compound 7A (+)-(2R,3R)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-2-METHYLBUTAN-1-OL
Compound 7A (2S,3S)-3-(4-METHOXYPHENYLAMINO)-4,4,4-TRIFLUORO-2-METHYLBUTAN-1-OL
Compound 7B (2S,3S)-3-(4-METHOXYPHENYLAMINO)-4,4,5,5,5-PENTAFLUORO-2-METHYLPENTAN-1-OL
Compound 7C (-)-(3S)-4,4,4-TRIFLUORO-3-(4-METHOXYANILINO)-BUTAN-1-OL
Compound 9A (2S*,3S*)-3-AMINO-2-ETHYL-4,4,4-TRIFLUORO-BUTANOIC-ACID
Compound 9B (2S*,3S*)-3-AMINO-4,4,4-TRIFLUORO-2-METHYLBUTANOIC-ACID
#-4U;(Z)-Enamino-tautomer;(-)-(2S,5S,1R)-5-methyl-2-(1-methyl-1-phenylethyl)-cyclohexyl-(Z)-4-chloro-4,4-difluoro-3-(4-methoxyanilino)-2-methyl-2-butenoate
Citation
| Citation | J.ORG.CHEM.,67,4667(2002) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| Issue | 14 |
| Volume | 67 |
| Page(s) | 4667-4679 |
| Year | 2002 |
| Author(s) | Santos Fustero, Belén Pina, Esther Salavert, Antonio Navarro, M. Carmen Ramírez de Arellano, Antonio Simón Fuentes |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/jo025621k |