Spectra for:
Fabienne Grellepois, Fatima Chorki, Benoit Crousse, Michèle Ourévitch, Danièle Bonnet-Delpon, Jean-Pierre Bégué
Compound 2 (1S,4R,5R,8R,12R,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADEC-2-ENE
![(1S,4R,5R,8R,12R,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADEC-2-ENE](/api/compound/DOyH6MZATbx.png?h=300&w=458 "(1S,4R,5R,8R,12R,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADEC-2-ENE")
Compound 5 (1S,4R,5R,8R,9R,10R,12R,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADECAN-10-OL
![(1S,4R,5R,8R,9R,10R,12R,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADECAN-10-OL](/api/compound/zDKV2eNITl.png?h=300&w=458 "(1S,4R,5R,8R,9R,10R,12R,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADECAN-10-OL")
Compound 8-ALPHA (1S,4R,5S,8R,9R,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADECANE-9-CARBALDEHYDE
![(1S,4R,5S,8R,9R,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADECANE-9-CARBALDEHYDE](/api/compound/KnxXzQiQH4I.png?h=300&w=458 "(1S,4R,5S,8R,9R,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADECANE-9-CARBALDEHYDE")
Compound 8-BETA (1S,4R,5S,8R,9S,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADECANE-9-CARBALDEHYDE
![(1S,4R,5S,8R,9S,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADECANE-9-CARBALDEHYDE](/api/compound/K5KfKZT7S78.png?h=300&w=458 "(1S,4R,5S,8R,9S,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADECANE-9-CARBALDEHYDE")
Compound 9-ALPHA 2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9R,11R,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADEC-9-YL]-1-ETANONE
![2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9R,11R,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADEC-9-YL]-1-ETANONE](/api/compound/HPX1Wa9fiY7.png?h=300&w=458 "2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9R,11R,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADEC-9-YL]-1-ETANONE")
Compound 9-BETA 2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9S,11R,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADEC-9-YL]-1-ETANONE
![2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9S,11R,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADEC-9-YL]-1-ETANONE](/api/compound/AyWHys0vC2h.png?h=300&w=458 "2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9S,11R,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTADEC-9-YL]-1-ETANONE")
Compound 11 (1R,3R,5R,6R,9R,10R,13S,16R)-5,9,13-TRIMETHYL-3-(TRIFLUOROMETHYL)-2,4,14,15,17-PENTAOXAPENTACYCLO-[11.3.1.0.(3,5)0.(6,16)0(10,16)]-HEPTADECANE
![(1R,3R,5R,6R,9R,10R,13S,16R)-5,9,13-TRIMETHYL-3-(TRIFLUOROMETHYL)-2,4,14,15,17-PENTAOXAPENTACYCLO-[11.3.1.0.(3,5)0.(6,16)0(10,16)]-HEPTADECANE](/api/compound/86N7iVSoLs6.png?h=300&w=458 "(1R,3R,5R,6R,9R,10R,13S,16R)-5,9,13-TRIMETHYL-3-(TRIFLUOROMETHYL)-2,4,14,15,17-PENTAOXAPENTACYCLO-[11.3.1.0.(3,5)0.(6,16)0(10,16)]-HEPTADECANE")
#12-ALPHA+13-ALPHA;MAJOR-ISOMER;(1S,1R)-2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9R,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENT
![#12-ALPHA+13-ALPHA;MAJOR-ISOMER;(1S,1R)-2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9R,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENT](/api/compound/JHFs9ulNjds.png?h=300&w=458 "#12-ALPHA+13-ALPHA;MAJOR-ISOMER;(1S,1R)-2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9R,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENT")
#12-BETA+13-BETA;MAJOR-ISOMER;(1S,1R)-2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9S,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTAD
![#12-BETA+13-BETA;MAJOR-ISOMER;(1S,1R)-2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9S,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTAD](/api/compound/33rBQIcRy9M.png?h=300&w=458 "#12-BETA+13-BETA;MAJOR-ISOMER;(1S,1R)-2,2,2-TRIFLUORO-1-[(1S,4R,5S,8R,9S,11S,12S)-1,5,9-TRIMETHYL-10,13,14,15-TETRAOXATETRACYCLO-[9.3.1.0.(4,12)0(8,12)]-PENTAD")
#14B;(1S,4R,5S,8R,9S,10R,12S,13S)-1,5,9-TRIMETHYL-10-[2,2,2-TRIFLUORO-1-(TRIFLUOROMETHYL)-ETHOXY]-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-H
![#14B;(1S,4R,5S,8R,9S,10R,12S,13S)-1,5,9-TRIMETHYL-10-[2,2,2-TRIFLUORO-1-(TRIFLUOROMETHYL)-ETHOXY]-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-H](/api/compound/IaXZeH0TStx.png?h=300&w=458 "#14B;(1S,4R,5S,8R,9S,10R,12S,13S)-1,5,9-TRIMETHYL-10-[2,2,2-TRIFLUORO-1-(TRIFLUOROMETHYL)-ETHOXY]-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-H")
#15-BETA;MAJOR-ISOMER;(1S,4R,5S,8S,9S,10R,12R,13S)-9-BROMO-1,5,9-TRIMETHYL-10-(2,2,2-TRIFLUOROETHOXY)-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)-HE
#15-BETA;MINOR-ISOMER;(1S,4R,5S,8S,9S,10R,12R,13S)-9-BROMO-1,5,9-TRIMETHYL-10-(2,2,2-TRIFLUOROETHOXY)-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)-HE
#6;TRIMETHYLSILYL-(1S,4R,5R,8R,9R,10R,12S,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADEC-10-YL-ETHER
![#6;TRIMETHYLSILYL-(1S,4R,5R,8R,9R,10R,12S,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADEC-10-YL-ETHER](/api/compound/IMvJLT1NsgS.png?h=300&w=458 "#6;TRIMETHYLSILYL-(1S,4R,5R,8R,9R,10R,12S,13R)-1,5,9-TRIMETHYL-10-(TRIFLUOROMETHYL)-11,14,15,16-TETRAOXATETRACYCLO-[10.3.1.0.(4,13)0(8,13)]-HEXADEC-10-YL-ETHER")
Citation
| Citation | J.ORG.CHEM.,67,1253(2002) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| Issue | 4 |
| Volume | 67 |
| Page(s) | 1253-1260 |
| Year | 2002 |
| Author(s) | Fabienne Grellepois, Fatima Chorki, Benoit Crousse, Michèle Ourévitch, Danièle Bonnet-Delpon, Jean-Pierre Bégué |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/jo016091f |