Spectra for:
Christoph Gaul, Kaspar Sch�rer, Dieter Seebach
Compound 2 (S)-4-ISOPROPYL-3-(METHOXYMETHYL)-5,5-DIPHENYLOXAZOLIDIN-2-ONE
Compound 3 (S)-4-ISOPROPYL-3-(METHYLSULFANYLMETHYL)-5,5-DIPHENYLOXAZOLIDIN-2-ONE
Compound 4 (S)-4-ISOPROPYL-5,5-DIPHENYL-3-(PHENYLSULFANYLMETHYL)-OXAZOLIDIN-2-ONE
Compound 6 (S)-4-ISOPROPYL-3-[[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIN-3-YL]-METHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-4-ISOPROPYL-3-[[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIN-3-YL]-METHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/KtN5ydYQYoQ.png?h=300&w=458 "(S)-4-ISOPROPYL-3-[[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIN-3-YL]-METHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 7B (S)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/8Im5f5fFIjK.png?h=300&w=458 "(S)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 7C (S)-3-[(1S,2S)-2-HYDROXY-2-PHENYL-1-(PHENYLSULFANYL)-ETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(1S,2S)-2-HYDROXY-2-PHENYL-1-(PHENYLSULFANYL)-ETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/FoFLWDYO2y2.png?h=300&w=458 "(S)-3-[(1S,2S)-2-HYDROXY-2-PHENYL-1-(PHENYLSULFANYL)-ETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 9K (S)-3-[(1S,2S)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUT-3-ENYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(1S,2S)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUT-3-ENYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/GjWEv9va77m.png?h=300&w=458 "(S)-3-[(1S,2S)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUT-3-ENYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 9M (S)-3-[(1S,2S)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(1S,2S)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/A2BQvqXExSG.png?h=300&w=458 "(S)-3-[(1S,2S)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 10M (S)-3-[(1S,2R)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(1S,2R)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/C2LgXGxndKv.png?h=300&w=458 "(S)-3-[(1S,2R)-2-HYDROXY-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 11A (S)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-3-PHENYLPROPYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-3-PHENYLPROPYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/AWJyuHSnCS8.png?h=300&w=458 "(S)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-3-PHENYLPROPYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 11B (S)-4-ISOPROPYL-5,5-DIPHENYL-3-[(1S,2R)-3,3,3-TRIFLUORO-2-HYDROXY-1-METHYLSULFANYL-2-PHENYLPROPYL]-OXAZOLIDIN-2-ONE
![(S)-4-ISOPROPYL-5,5-DIPHENYL-3-[(1S,2R)-3,3,3-TRIFLUORO-2-HYDROXY-1-METHYLSULFANYL-2-PHENYLPROPYL]-OXAZOLIDIN-2-ONE](/api/compound/653evYh9mvT.png?h=300&w=458 "(S)-4-ISOPROPYL-5,5-DIPHENYL-3-[(1S,2R)-3,3,3-TRIFLUORO-2-HYDROXY-1-METHYLSULFANYL-2-PHENYLPROPYL]-OXAZOLIDIN-2-ONE")
Compound 13 (S)-4-ISOPROPYL-3-[(1S,2R)-2-METHYL-1-(METHYLSULFANYL)-4-OXO-2,4-DIPHENYLBUTYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-4-ISOPROPYL-3-[(1S,2R)-2-METHYL-1-(METHYLSULFANYL)-4-OXO-2,4-DIPHENYLBUTYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/ImIc3TOzPZX.png?h=300&w=458 "(S)-4-ISOPROPYL-3-[(1S,2R)-2-METHYL-1-(METHYLSULFANYL)-4-OXO-2,4-DIPHENYLBUTYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 14A N-[(1S,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-PHENYLETHYL]-DIPHENYLPHOSPHINAMIDE
![N-[(1S,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-PHENYLETHYL]-DIPHENYLPHOSPHINAMIDE](/api/compound/H6wEs1RM46Q.png?h=300&w=458 "N-[(1S,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-PHENYLETHYL]-DIPHENYLPHOSPHINAMIDE")
Compound 14C N-[(1S,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-PHENYLETHYL]-2,4,6-TRIMETHYL-BENZENESULFONAMIDE
![N-[(1S,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-PHENYLETHYL]-2,4,6-TRIMETHYL-BENZENESULFONAMIDE](/api/compound/DdFVxS6cPsq.png?h=300&w=458 "N-[(1S,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-PHENYLETHYL]-2,4,6-TRIMETHYL-BENZENESULFONAMIDE")
Compound 15D N-[(1R,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-ISOPROPYLETHYL]-2,4,6-TRIMETHYL-BENZENESULFONAMIDE
![N-[(1R,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-ISOPROPYLETHYL]-2,4,6-TRIMETHYL-BENZENESULFONAMIDE](/api/compound/167wklKnk5z.png?h=300&w=458 "N-[(1R,2S)-2-[(S)-4-ISOPROPYL-2-OXO-5,5-DIPHENYLOXAZOLIDIN-3-YL]-2-METHYL-SULFANYL-1-ISOPROPYLETHYL]-2,4,6-TRIMETHYL-BENZENESULFONAMIDE")
Compound 16 (S)-4-ISOPROPYL-3-[(1S,2S)-2-(METHOXYMETHOXY)-1-(METHYLSULFANYL)-2-PHENYLETHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-4-ISOPROPYL-3-[(1S,2S)-2-(METHOXYMETHOXY)-1-(METHYLSULFANYL)-2-PHENYLETHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/ShqKFZtRiY.png?h=300&w=458 "(S)-4-ISOPROPYL-3-[(1S,2S)-2-(METHOXYMETHOXY)-1-(METHYLSULFANYL)-2-PHENYLETHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 17 (S)-3-[(1S,2S)-2-BENZYLOXY-3-METHYL-1-(METHYLSULFANYL)-BUT-3-ENYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(1S,2S)-2-BENZYLOXY-3-METHYL-1-(METHYLSULFANYL)-BUT-3-ENYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/1claBYT42wj.png?h=300&w=458 "(S)-3-[(1S,2S)-2-BENZYLOXY-3-METHYL-1-(METHYLSULFANYL)-BUT-3-ENYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 18 (S)-3-[(1S,2S)-2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(1S,2S)-2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/HWwl0pQRfcM.png?h=300&w=458 "(S)-3-[(1S,2S)-2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-3-METHYL-1-(METHYLSULFANYL)-BUTYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 22 (S)-2-Benzyloxy-3-methylbut-3-en-1-ol
Compound 28 (2R,3S)-3-(TERT.-BUTYLDIMETHYLSILANYLOXY)-4-METHYLPENTAN-2-OL
Compound 29 (1S,2S)-2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-3-METHYL-1-PHENYLBUTAN-1-OL;MINOR-DIASTEREOMER
Compound 29 (1R,2S)-2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-3-METHYL-1-PHENYLBUTAN-1-OL;MAJOR-DIASTEREOMER
Compound 30 (S)-4-ISOPROPYL-3-[(S)-METHOXYMETHOXY-PHENYLACETYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-4-ISOPROPYL-3-[(S)-METHOXYMETHOXY-PHENYLACETYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/KjoS1m2S4pE.png?h=300&w=458 "(S)-4-ISOPROPYL-3-[(S)-METHOXYMETHOXY-PHENYLACETYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 31 (S)-3-[(S)-2-BENZYLOXY-3-METHYLBUT-3-ENOYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(S)-2-BENZYLOXY-3-METHYLBUT-3-ENOYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/8aRFsUzeUAE.png?h=300&w=458 "(S)-3-[(S)-2-BENZYLOXY-3-METHYLBUT-3-ENOYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 33 (S)-2-(Benzyloxy)-3-methylbut-3-enoic acid methyl ester
Compound 34 (E,R)-4-HYDROXY-4-PHENYLPENT-2-ENOIC-ACID-METHYLESTER
Compound 35 (R)-5-METHYL-5-PHENYL-5H-FURAN-2-ONE
Compound 36 (S)-3-[(2S,3R)-3,5-DIPHENYL-2,3-DIHYDROFURAN-2-YL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[(2S,3R)-3,5-DIPHENYL-2,3-DIHYDROFURAN-2-YL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/7kJvXn5t7wa.png?h=300&w=458 "(S)-3-[(2S,3R)-3,5-DIPHENYL-2,3-DIHYDROFURAN-2-YL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 37 ISOPROPYL-3-[(1S,2S,3R,5R)-5-METHOXY-3,5-DIPHENYLTETRAHYDROFURAN-2-YL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![ISOPROPYL-3-[(1S,2S,3R,5R)-5-METHOXY-3,5-DIPHENYLTETRAHYDROFURAN-2-YL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/38j3k4g0wyj.png?h=300&w=458 "ISOPROPYL-3-[(1S,2S,3R,5R)-5-METHOXY-3,5-DIPHENYLTETRAHYDROFURAN-2-YL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 38 (S)-4-ISOPROPYL-3-(1-METHYLSULFANYLETHYL)-5,5-DIPHENYLOXAZOLIDIN-2-ONE
Compound 39 (S)-4-TERT.-BUTYL-3-(METHYLSULFANYLMETHYL)-5,5-DIPHENYLOXAZOLIDIN-2-ONE
Compound 40 (R)-3-(METHYLSULFANYLMETHYL)-4,5,5-TRIPHENYLOXAZOLIDIN-2-ONE
Compound 41 (4S,5R)-4-ISOPROPYL-3-(METHYLSULFANYLMETHYL)-5-PHENYLOXAZOLIDIN-2-ONE
Compound 42 (S)-3-[2-HYDROXY-1-METHYL-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-3-[2-HYDROXY-1-METHYL-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/6dZ4eBWFXBH.png?h=300&w=458 "(S)-3-[2-HYDROXY-1-METHYL-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 43 3-[(S)-1-(HYDROXYDIPHENYLMETHYL)-2-METHYLPROPYL]-4-METHYL-4-(METHYLSULFANYL)-5-PHENYLOXAZOLIDIN-2-ONE
![3-[(S)-1-(HYDROXYDIPHENYLMETHYL)-2-METHYLPROPYL]-4-METHYL-4-(METHYLSULFANYL)-5-PHENYLOXAZOLIDIN-2-ONE](/api/compound/GGoJ9JBGux7.png?h=300&w=458 "3-[(S)-1-(HYDROXYDIPHENYLMETHYL)-2-METHYLPROPYL]-4-METHYL-4-(METHYLSULFANYL)-5-PHENYLOXAZOLIDIN-2-ONE")
Compound 44 (S)-4-TERT.-BUTYL-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE
![(S)-4-TERT.-BUTYL-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE](/api/compound/Kd8KjN9J0VH.png?h=300&w=458 "(S)-4-TERT.-BUTYL-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-5,5-DIPHENYLOXAZOLIDIN-2-ONE")
Compound 45 (R)-3-[(1R,2R)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4,5,5-TRIPHENYLOXAZOLIDIN-2-ONE
![(R)-3-[(1R,2R)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4,5,5-TRIPHENYLOXAZOLIDIN-2-ONE](/api/compound/45KCdW2StFX.png?h=300&w=458 "(R)-3-[(1R,2R)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4,5,5-TRIPHENYLOXAZOLIDIN-2-ONE")
Compound 46 (4S,5R)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5-PHENYLOXAZOLIDIN-2-ONE
![(4S,5R)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5-PHENYLOXAZOLIDIN-2-ONE](/api/compound/4L1IFtbtUqG.png?h=300&w=458 "(4S,5R)-3-[(1S,2S)-2-HYDROXY-1-(METHYLSULFANYL)-2-PHENYLETHYL]-4-ISOPROPYL-5-PHENYLOXAZOLIDIN-2-ONE")
Citation
| Citation | J.ORG.CHEM.,66,3059(2001) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| Issue | 9 |
| Volume | 66 |
| Page(s) | 3059-3073 |
| Year | 2001 |
| Author(s) | Christoph Gaul, Kaspar Sch�rer, Dieter Seebach |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/jo0155254 |