Spectra for:
Helen Y. Wu, Keith A. M. Walker, Janis T. Nelson
Compound 6 8-EXO-CHLORO-8-ENDOMETHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE
![8-EXO-CHLORO-8-ENDOMETHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE](/api/compound/35ixbHPpDNp.png?h=300&w=458 "8-EXO-CHLORO-8-ENDOMETHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE")
Compound 7 8-ENDO-CHLORO-8-EXO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE
![8-ENDO-CHLORO-8-EXO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE](/api/compound/2kaRMNx86pA.png?h=300&w=458 "8-ENDO-CHLORO-8-EXO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE")
Compound 8 8-ENDO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE
![8-ENDO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE](/api/compound/F8Ag0ifRRhR.png?h=300&w=458 "8-ENDO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7-ONE")
Compound 10 SPIRO-[8-ENDO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7,2'-(1',3'-DIOXOLANE)]
![SPIRO-[8-ENDO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7,2'-(1',3'-DIOXOLANE)]](/api/compound/K9kpTM5We3W.png?h=300&w=458 "SPIRO-[8-ENDO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7,2'-(1',3'-DIOXOLANE)]")
Compound 11 SPIRO-[8-EXO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7,2'-(1',3'-DIOXOLANE)]
![SPIRO-[8-EXO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7,2'-(1',3'-DIOXOLANE)]](/api/compound/FOcolrnHCxb.png?h=300&w=458 "SPIRO-[8-EXO-METHYLBICYClO-[4.2.0]-OCT-2-EN-7,2'-(1',3'-DIOXOLANE)]")
Compound 12 (1S*,2S*,4R*,7S*)-SPIRO-[3-OXA-9-ENDO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]
![(1S*,2S*,4R*,7S*)-SPIRO-[3-OXA-9-ENDO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]](/api/compound/F4UnnMC5ds6.png?h=300&w=458 "(1S*,2S*,4R*,7S*)-SPIRO-[3-OXA-9-ENDO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]")
Compound 13 (1S*,2R*,4R*,7S*)-SPIRO-[3-OXA-9-ENDO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]
![(1S*,2R*,4R*,7S*)-SPIRO-[3-OXA-9-ENDO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]](/api/compound/CueQnQXhb5i.png?h=300&w=458 "(1S*,2R*,4R*,7S*)-SPIRO-[3-OXA-9-ENDO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]")
Compound 14 (1S*,2S*,4R*,7S*)-SPIRO-[3-OXA-9-EXO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]
![(1S*,2S*,4R*,7S*)-SPIRO-[3-OXA-9-EXO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]](/api/compound/AeCI3TNte9a.png?h=300&w=458 "(1S*,2S*,4R*,7S*)-SPIRO-[3-OXA-9-EXO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]")
Compound 15 (1S*,2R*,4S*,7S*)-SPIRO-[3-OXA-9-EXO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]
![(1S*,2R*,4S*,7S*)-SPIRO-[3-OXA-9-EXO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]](/api/compound/4DrJpPFLu8n.png?h=300&w=458 "(1S*,2R*,4S*,7S*)-SPIRO-[3-OXA-9-EXO-METHYLBICYClO-[5.2.0.0(2,4)]-NONANE-8,2'-(1',3'-DIOXOLANE)]")
Compound 22 SPIRO-[3-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDRXY-8-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]
![SPIRO-[3-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDRXY-8-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]](/api/compound/8K2jVXKD2DW.png?h=300&w=458 "SPIRO-[3-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDRXY-8-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]")
Compound 23 SPIRO-[3-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDRXY-8-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]
![SPIRO-[3-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDRXY-8-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]](/api/compound/AxTJPaRKPCZ.png?h=300&w=458 "SPIRO-[3-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDRXY-8-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]")
Compound 24 (3'S,1S,2S,3R,6S)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE
![(3'S,1S,2S,3R,6S)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE](/api/compound/BazOa5Ppt0o.png?h=300&w=458 "(3'S,1S,2S,3R,6S)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE")
Compound 25 (3'S,1R,2R,3S,6R)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE
![(3'S,1R,2R,3S,6R)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE](/api/compound/BEKJS2zjCWT.png?h=300&w=458 "(3'S,1R,2R,3S,6R)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE")
Compound 26 (3'S,1S,2S,3R,6S)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE
![(3'S,1S,2S,3R,6S)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE](/api/compound/KoDdkJ4nbbH.png?h=300&w=458 "(3'S,1S,2S,3R,6S)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE")
Compound 27 (3'S,1R,2R,3S,6R)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE
![(3'S,1R,2R,3S,6R)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE](/api/compound/20AkdpTTqyQ.png?h=300&w=458 "(3'S,1R,2R,3S,6R)-2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7-ONE")
Compound 30 (E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID
![(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID](/api/compound/LKMHOajLAJ7.png?h=300&w=458 "(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID")
Compound 34 (E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-PENTANOIC-ACID
![(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-PENTANOIC-ACID](/api/compound/FrAbfoDFIJz.png?h=300&w=458 "(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-PENTANOIC-ACID")
Compound 49 (Z)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHOXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID
![(Z)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHOXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID](/api/compound/9RPFanYVeNB.png?h=300&w=458 "(Z)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHOXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID")
Compound 52 (E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-EXO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID
![(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-EXO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID](/api/compound/9QAfvdebiXV.png?h=300&w=458 "(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-EXO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID")
Compound 53 (Z)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID
![(Z)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID](/api/compound/LabHLazG8Ka.png?h=300&w=458 "(Z)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID")
Compound 55 (E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID
![(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID](/api/compound/4Z8xrvX9VNW.png?h=300&w=458 "(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID")
Compound 55 (E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID
![(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID](/api/compound/9CcOrChunEC.png?h=300&w=458 "(E)-(3'S,1S,2S,3R,6S)-4-[2-(3'-HYDROXY-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-6-METHYL-8-ENDO-METHYLBICYClO-[4.2.0]-OCT-7-YLIDENE]-BUTANOIC-ACID")
#16;(3'S,1S,2S,3R,6S)-SPIRO-[2-[3'-[(TERT-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLA
![#16;(3'S,1S,2S,3R,6S)-SPIRO-[2-[3'-[(TERT-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLA](/api/compound/E2HvAkWhUf5.png?h=300&w=458 "#16;(3'S,1S,2S,3R,6S)-SPIRO-[2-[3'-[(TERT-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLA")
#17;(3'S,1R,2R,3S,6R)-SPIRO-[2-[3'-[(TERT-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLA
![#17;(3'S,1R,2R,3S,6R)-SPIRO-[2-[3'-[(TERT-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLA](/api/compound/CqdId4PD4yj.png?h=300&w=458 "#17;(3'S,1R,2R,3S,6R)-SPIRO-[2-[3'-[(TERT-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-ENDO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLA")
(3'S,1R,2R,3S,6R)-SPIRO-[2-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]
![(3'S,1R,2R,3S,6R)-SPIRO-[2-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]](/api/compound/4MwOP8XmtVs.png?h=300&w=458 "(3'S,1R,2R,3S,6R)-SPIRO-[2-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]")
(3'S,1S,2S,3R,6S)-SPIRO-[2-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]
![(3'S,1S,2S,3R,6S)-SPIRO-[2-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]](/api/compound/38ikoKgKFbZ.png?h=300&w=458 "(3'S,1S,2S,3R,6S)-SPIRO-[2-[3'-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-3'-CYClOHEXYLPROP-1'-YNYL]-3-HYDROXY-8-EXO-METHYLBICYClO-[4.2.0]-OCTANE-7,2''-(1'',3''-DIOXOLANE)]")
Citation
| Citation | J.ORG.CHEM.,59,1389(1994) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| Issue | 6 |
| Volume | 59 |
| Page(s) | 1389-1395 |
| Year | 1994 |
| Author(s) | Helen Y. Wu, Keith A. M. Walker, Janis T. Nelson |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/jo00085a031 |