Spectra for:
Scott E. Denmark, Mark E. Schnute, C. B. W. Senanayake
Compound 6 (1R,2S)-TRANS-[(2-PHENYLCYCLOHEXYL)-OXY]-ETHENE
![(1R,2S)-TRANS-[(2-PHENYLCYCLOHEXYL)-OXY]-ETHENE](/api/compound/1JfjJMjNRTr.png?h=300&w=458 "(1R,2S)-TRANS-[(2-PHENYLCYCLOHEXYL)-OXY]-ETHENE")
Compound 7 (1S,3R,5S,5AS,7AS,7BR)-OCTAHYDRO-1-HYDROXY-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE
![(1S,3R,5S,5AS,7AS,7BR)-OCTAHYDRO-1-HYDROXY-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE](/api/compound/62TZX3ORLUp.png?h=300&w=458 "(1S,3R,5S,5AS,7AS,7BR)-OCTAHYDRO-1-HYDROXY-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE")
Compound 7 (1S,3R,5S,5AR,7AS,7BR)-OCTAHYDRO-1-HYDROXY-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE
![(1S,3R,5S,5AR,7AS,7BR)-OCTAHYDRO-1-HYDROXY-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE](/api/compound/8GSklUik18O.png?h=300&w=458 "(1S,3R,5S,5AR,7AS,7BR)-OCTAHYDRO-1-HYDROXY-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE")
Compound 10 (1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE
![(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE](/api/compound/KkFOowXT6lo.png?h=300&w=458 "(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE")
Compound 11(E) (1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-2-[1-(E)-PROPENYLOXY]-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE
![(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-2-[1-(E)-PROPENYLOXY]-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE](/api/compound/LP61Ge7guBZ.png?h=300&w=458 "(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-2-[1-(E)-PROPENYLOXY]-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE")
Compound 11(Z) (1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-2-[1-(Z)-PROPENYLOXY]-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE
![(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-2-[1-(Z)-PROPENYLOXY]-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE](/api/compound/Ll7B3YpqGJV.png?h=300&w=458 "(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-2-[1-(Z)-PROPENYLOXY]-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPTANE")
Compound 12 (1R,2S)-TRANS-2-PHENYL-1-(1-PROPYNYLOXY)-CYCLOHEXANE
Compound 13(E) (1R,2S)-TRANS-2-PHENYL-1-[1-(E)-PROPENYLOXY]-CYCLOHEXANE
![(1R,2S)-TRANS-2-PHENYL-1-[1-(E)-PROPENYLOXY]-CYCLOHEXANE](/api/compound/8UOOWo7tzqp.png?h=300&w=458 "(1R,2S)-TRANS-2-PHENYL-1-[1-(E)-PROPENYLOXY]-CYCLOHEXANE")
Compound 13(Z) (1R,2S)-TRANS-2-PHENYL-1-[1-(Z)-PROPENYLOXY]-CYCLOHEXANE
![(1R,2S)-TRANS-2-PHENYL-1-[1-(Z)-PROPENYLOXY]-CYCLOHEXANE](/api/compound/IPKYzLqJUoe.png?h=300&w=458 "(1R,2S)-TRANS-2-PHENYL-1-[1-(Z)-PROPENYLOXY]-CYCLOHEXANE")
Compound 19 REL-(1S,3R,5S,5AS,7AS,7BR)-OCTAHYDRO-1-[N-(3,5-DINITROPHENYL)-CARBAMOXY]-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE
![REL-(1S,3R,5S,5AS,7AS,7BR)-OCTAHYDRO-1-[N-(3,5-DINITROPHENYL)-CARBAMOXY]-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE](/api/compound/8vt4caTEmmP.png?h=300&w=458 "REL-(1S,3R,5S,5AS,7AS,7BR)-OCTAHYDRO-1-[N-(3,5-DINITROPHENYL)-CARBAMOXY]-5,7B-DIMETHYL-2H-CYCLOPENTA-[GH]-PYRROLIZIN-2-ONE")
#14-ALPHA;(2S,2AS,4AS,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER
![#14-ALPHA;(2S,2AS,4AS,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER](/api/compound/JVYkXxaimq0.png?h=300&w=458 "#14-ALPHA;(2S,2AS,4AS,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER")
#14-BETA';(2R,2AR,4AR,6R,7AR,7BS)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER
![#14-BETA';(2R,2AR,4AR,6R,7AR,7BS)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER](/api/compound/G7Hv6Ffp0et.png?h=300&w=458 "#14-BETA';(2R,2AR,4AR,6R,7AR,7BS)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER")
#16-BETA';(2R,4AR,6R,7AR,7BR)-6-[(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPT-2-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT
![#16-BETA';(2R,4AR,6R,7AR,7BR)-6-[(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPT-2-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT](/api/compound/CoM7Bhuui3o.png?h=300&w=458 "#16-BETA';(2R,4AR,6R,7AR,7BR)-6-[(1S,2R,3S,4R)-3-(2,2-DIMETHYLPROPOXY)-4,7,7-TRIMETHYLBICYCLO-[2.2.1]-HEPT-2-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT")
#21;(2S,2AS,4AS,5S,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER
![#21;(2S,2AS,4AS,5S,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER](/api/compound/DTjw6F9I9Px.png?h=300&w=458 "#21;(2S,2AS,4AS,5S,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER")
#22;(2S,2AS,4AS,5R,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER
![#22;(2S,2AS,4AS,5R,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER](/api/compound/BRIcn6lPO1o.png?h=300&w=458 "#22;(2S,2AS,4AS,5R,6S,7AR,7BR)-6-[(1R,2S)-(2-PHENYLCYCLOHEXYL)-OXY]-OCTAHYDRO-7B-METHYL-1,7-DIOXA-7A-AZACYCLOPENT-[CD]-INDANE-2-CARBOXYLIC-ACID-METHYLESTER")
Citation
| Citation | J.ORG.CHEM.,58,1859(1993) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| Issue | 7 |
| Volume | 58 |
| Page(s) | 1859-1874 |
| Year | 1993 |
| Author(s) | Scott E. Denmark, Mark E. Schnute, C. B. W. Senanayake |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/jo00059a044 |