Spectra for:
Edward E. Korshin, Yaroslav V. Bilokin, Hailin Zheng, Mario D. Bachi
Compound 9 DIETHYL-2-[(1S,2S/R,5S)-6-TOSYL-3-THIA-6-AZABICYCLO-[3.2.1]-OCT-2-YL]-MALONATE;MAJOR-ISOMER
![DIETHYL-2-[(1S,2S/R,5S)-6-TOSYL-3-THIA-6-AZABICYCLO-[3.2.1]-OCT-2-YL]-MALONATE;MAJOR-ISOMER](/api/compound/K5CgIOegyz6.png?h=300&w=458 "DIETHYL-2-[(1S,2S/R,5S)-6-TOSYL-3-THIA-6-AZABICYCLO-[3.2.1]-OCT-2-YL]-MALONATE;MAJOR-ISOMER")
Compound 10 (2S,4R)-2-(ACETYLSULFANYLMETHYL)-1-(4-METHYLPHENYLSULFONYL)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-PYRROLIDINE;MAJOR-ISOMER
![(2S,4R)-2-(ACETYLSULFANYLMETHYL)-1-(4-METHYLPHENYLSULFONYL)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-PYRROLIDINE;MAJOR-ISOMER](/api/compound/2EbHEz4fF0P.png?h=300&w=458 "(2S,4R)-2-(ACETYLSULFANYLMETHYL)-1-(4-METHYLPHENYLSULFONYL)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-PYRROLIDINE;MAJOR-ISOMER")
Compound 12A (E)-(2S,4R)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MAJOR-ISOMER
![(E)-(2S,4R)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MAJOR-ISOMER](/api/compound/ARgjGaHsUUz.png?h=300&w=458 "(E)-(2S,4R)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MAJOR-ISOMER")
Compound 12B (Z)-(2S,4R)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MINOR-ISOMER
![(Z)-(2S,4R)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MINOR-ISOMER](/api/compound/8KNT6ABdBJG.png?h=300&w=458 "(Z)-(2S,4R)-4-[2,2-BIS-(ETHOXYCARBONYL)-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MINOR-ISOMER")
Compound 13A (2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MAJOR-ISOMER
![(2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MAJOR-ISOMER](/api/compound/HWxVRgzH5pm.png?h=300&w=458 "(2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MAJOR-ISOMER")
Compound 13B (2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MINOR-ISOMER
![(2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MINOR-ISOMER](/api/compound/2G59uofZo4u.png?h=300&w=458 "(2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MINOR-ISOMER")
Compound 14A (E)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-ISOMER
![(E)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-ISOMER](/api/compound/EWte1qTSSji.png?h=300&w=458 "(E)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-ISOMER")
Compound 14B (Z)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MINOR-ISOMER
![(Z)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MINOR-ISOMER](/api/compound/LxA2g7mrnXU.png?h=300&w=458 "(Z)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-2-[(Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MINOR-ISOMER")
Compound 15A+15B (2S,4R)-4-[(E)-2-METHYLOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E/Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MIXTURE
![(2S,4R)-4-[(E)-2-METHYLOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E/Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MIXTURE](/api/compound/LmbJBIPbhpc.png?h=300&w=458 "(2S,4R)-4-[(E)-2-METHYLOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E/Z)-2-PHENYL-1-ETHENYLSULFANYLMETHYL]-PYRROLIDINE;MIXTURE")
Compound 16A (E)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-(METHYLPHENYLSULFONYL)-1-ETHENYL]-2-[(E)-(2-PHENYL-1-ETHENYL)-SULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-I
![(E)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-(METHYLPHENYLSULFONYL)-1-ETHENYL]-2-[(E)-(2-PHENYL-1-ETHENYL)-SULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-I](/api/compound/LrhCkS2T6jE.png?h=300&w=458 "(E)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-(METHYLPHENYLSULFONYL)-1-ETHENYL]-2-[(E)-(2-PHENYL-1-ETHENYL)-SULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-I")
Compound 16B (Z)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-(METHYLPHENYLSULFONYL)-1-ETHENYL]-2-[(Z)-(2-PHENYL-1-ETHENYL)-SULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MINOR-I
![(Z)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-(METHYLPHENYLSULFONYL)-1-ETHENYL]-2-[(Z)-(2-PHENYL-1-ETHENYL)-SULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MINOR-I](/api/compound/OutjOXDGqy.png?h=300&w=458 "(Z)-TERT.-BUTYL-(2S,4R)-4-[(E)-2-(METHYLPHENYLSULFONYL)-1-ETHENYL]-2-[(Z)-(2-PHENYL-1-ETHENYL)-SULFANYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MINOR-I")
Compound 17A (2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE;LESS-POLAR-ISOMER
![(2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE;LESS-POLAR-ISOMER](/api/compound/7OIsJUow1qg.png?h=300&w=458 "(2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE;LESS-POLAR-ISOMER")
Compound 18A+18B TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHYLOXYCARBONYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MIXTURE
![TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHYLOXYCARBONYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MIXTURE](/api/compound/KA4qGYbVei.png?h=300&w=458 "TERT.-BUTYL-(2S,4R)-4-[(E)-2-METHYLOXYCARBONYL-1-ETHENYL]-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE-1-CARBOXYLATE;MIXTURE")
Compound 19A (2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE;LESS-POLAR-ISOMER
![(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE;LESS-POLAR-ISOMER](/api/compound/DqrXktw9NJi.png?h=300&w=458 "(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-[(E)-2-PHENYL-1-ETHENYLSULFINYLMETHYL]-PYRROLIDINE;LESS-POLAR-ISOMER")
Compound 20 (2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-PYRROLIDINECARBALDEHYDE
![(2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-PYRROLIDINECARBALDEHYDE](/api/compound/FixFvpG9Q6d.png?h=300&w=458 "(2S,4R)-1-(4-METHYLPHENYLSULFONYL)-4-[(E)-2-PHENYL-1-ETHENYL]-2-PYRROLIDINECARBALDEHYDE")
Compound 21 TERT.-BUTYL-(2S,4R)-2-FORMYL-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-ISOMER
![TERT.-BUTYL-(2S,4R)-2-FORMYL-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-ISOMER](/api/compound/62y1w6zBfCA.png?h=300&w=458 "TERT.-BUTYL-(2S,4R)-2-FORMYL-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-PYRROLIDINE-1-CARBOXYLATE;MAJOR-ISOMER")
Compound 22 (2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-PYRROLIDINECARBALDEHYDE
![(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-PYRROLIDINECARBALDEHYDE](/api/compound/2pcnnixF2GZ.png?h=300&w=458 "(2S,4R)-4-[(E)-2-METHOXYCARBONYL-1-ETHENYL]-1-(4-METHYLPHENYLSULFONYL)-2-PYRROLIDINECARBALDEHYDE")
Citation
| Citation | J.AM.CHEM.SOC.,126,2708(2004) |
|---|---|
| Journal | Journal of the American Chemical Society |
| Issue | 9 |
| Volume | 126 |
| Page(s) | 2708-2709 |
| Year | 2004 |
| Author(s) | Edward E. Korshin, Yaroslav V. Bilokin, Hailin Zheng, Mario D. Bachi |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ja031766c |