Spectra for:
Michael G. Organ, Robert D. J. Froese, John D. Goddard, Nicholas J. Taylor, Gordon L. Lange
Compound CIS-11 7-BETA-ACETYL-6-BETA-(FORMYLMETHYL)-6-ALPHA,7-BETA-DIHYDRO-1,4-DIOXASPIRO-[4.5]-DECANE;MINOR-ISOMER
![7-BETA-ACETYL-6-BETA-(FORMYLMETHYL)-6-ALPHA,7-BETA-DIHYDRO-1,4-DIOXASPIRO-[4.5]-DECANE;MINOR-ISOMER](/api/compound/Khuf7lwTAwz.png?h=300&w=458 "7-BETA-ACETYL-6-BETA-(FORMYLMETHYL)-6-ALPHA,7-BETA-DIHYDRO-1,4-DIOXASPIRO-[4.5]-DECANE;MINOR-ISOMER")
Compound CIS-12 1-ALPHA,6-ALPHA-DIHYDRO-5-ALPHA-METHYL-10-ALPHA,10-BETA-(ETHYLENEDIOXY)-4-OXABICYCLO-[4.4.0]-3-DECANONE;MINOR-EPIMER
![1-ALPHA,6-ALPHA-DIHYDRO-5-ALPHA-METHYL-10-ALPHA,10-BETA-(ETHYLENEDIOXY)-4-OXABICYCLO-[4.4.0]-3-DECANONE;MINOR-EPIMER](/api/compound/2aFSeHqQBeg.png?h=300&w=458 "1-ALPHA,6-ALPHA-DIHYDRO-5-ALPHA-METHYL-10-ALPHA,10-BETA-(ETHYLENEDIOXY)-4-OXABICYCLO-[4.4.0]-3-DECANONE;MINOR-EPIMER")
Compound TRANS-11 7-ALPHA-ACETYL-6-BETA-(FORMYLMETHYL)-6-ALPHA,7-BETA-DIHYDRO-1,4-DIOXASPIRO-[4.5]-DECANE;MAJOR-ISOMER
![7-ALPHA-ACETYL-6-BETA-(FORMYLMETHYL)-6-ALPHA,7-BETA-DIHYDRO-1,4-DIOXASPIRO-[4.5]-DECANE;MAJOR-ISOMER](/api/compound/372ulEQanOf.png?h=300&w=458 "7-ALPHA-ACETYL-6-BETA-(FORMYLMETHYL)-6-ALPHA,7-BETA-DIHYDRO-1,4-DIOXASPIRO-[4.5]-DECANE;MAJOR-ISOMER")
Compound TRANS-12 1-ALPHA,6-BETA-DIHYDRO-5-ALPHA-METHYL-10-ALPHA,10-BETA-(ETHYLENEDIOXY)-4-OXABICYCLO-[4.4.0]-3-DECANONE;MAJOR-EPIMER
![1-ALPHA,6-BETA-DIHYDRO-5-ALPHA-METHYL-10-ALPHA,10-BETA-(ETHYLENEDIOXY)-4-OXABICYCLO-[4.4.0]-3-DECANONE;MAJOR-EPIMER](/api/compound/E5mLEeIdoHc.png?h=300&w=458 "1-ALPHA,6-BETA-DIHYDRO-5-ALPHA-METHYL-10-ALPHA,10-BETA-(ETHYLENEDIOXY)-4-OXABICYCLO-[4.4.0]-3-DECANONE;MAJOR-EPIMER")
Compound 4 6-TERT.-BUTYL-5,6-DIHYDRO-4,6-DIMETHYL-2H-PYRAN-2-ONE
Compound 5 2-TERT.-BUTYL-2,3-DIHYDRO-2,6-DIMETHYL-4H-PYRAN-4-ONE
Compound 6A 6.beta.-n-Butyl-2.alpha.-tert-butyl-2.beta.,6.alpha.-dimethyl-1,3-dioxan-4-one
Compound 6B 2-ALPHA-TERT.-BUTYL-6-BETA-ETHYL-2-BETA,6-ALPHA-DIMETHYL-1,3-DIOXAN-4-ONE
Compound 7A 4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-ALPHA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE
![4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-ALPHA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE](/api/compound/HG3DIFPnlsP.png?h=300&w=458 "4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-ALPHA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE")
Compound 7B 4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-ALPHA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-9-ALPHA,9-BETA-(ETHYLENEDIOXY)-6-OXOTRICYCLO-[6.4.0.0(2,7)]-D
![4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-ALPHA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-9-ALPHA,9-BETA-(ETHYLENEDIOXY)-6-OXOTRICYCLO-[6.4.0.0(2,7)]-D](/api/compound/BGOtOIlrqeT.png?h=300&w=458 "4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-ALPHA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-9-ALPHA,9-BETA-(ETHYLENEDIOXY)-6-OXOTRICYCLO-[6.4.0.0(2,7)]-D")
Compound 8 4-ALPHA-TERT.-BUTYL-1-BETA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE
![4-ALPHA-TERT.-BUTYL-1-BETA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE](/api/compound/JHsmSXh8ibQ.png?h=300&w=458 "4-ALPHA-TERT.-BUTYL-1-BETA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE")
Compound 9A 4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE
![4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE](/api/compound/1KthmZzZ2z1.png?h=300&w=458 "4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DODECANE")
Compound 9B 4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-9-ALPHA,9-BETA-(ETHYLENEDIOXY)-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DO
![4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-9-ALPHA,9-BETA-(ETHYLENEDIOXY)-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DO](/api/compound/CFyriUN4k7C.png?h=300&w=458 "4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-BETA-TRIHYDRO-2-BETA,4-BETA-DIMETHYL-1,3-DIOXA-9-ALPHA,9-BETA-(ETHYLENEDIOXY)-6-OXOTRICYCLO-[6.4.0.0(2,7)]-DO")
Compound 10 4-ALPHA-TERT.-BUTYL-1-ALPHA,7-BETA,8-ALPHA-TRIHYDRO-2-BETA-METHYL-4-BETA-(DEUTERIOMETHYL)-3,5-DIOXA-9-ALPHA,9-BETA-(ETHYLENEDIOXY)-6-OXOTRICYCLO-[
Compound 13A 9.alpha.-tert-Butyl-1.beta.,2.alpha.,6.alpha.-trihydro-7.beta.,9.beta.-dimethyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane
![9.alpha.-tert-Butyl-1.beta.,2.alpha.,6.alpha.-trihydro-7.beta.,9.beta.-dimethyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane](/api/compound/HXbh6O8d1nF.png?h=300&w=458 "9.alpha.-tert-Butyl-1.beta.,2.alpha.,6.alpha.-trihydro-7.beta.,9.beta.-dimethyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane")
Compound 13B 9.alpha.-tert-Butyl-1.beta.,2.alpha.,6.alpha.,9.beta.-tetrahydro-7.beta.-methyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane
![9.alpha.-tert-Butyl-1.beta.,2.alpha.,6.alpha.,9.beta.-tetrahydro-7.beta.-methyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane](/api/compound/AVcGqp4Db9r.png?h=300&w=458 "9.alpha.-tert-Butyl-1.beta.,2.alpha.,6.alpha.,9.beta.-tetrahydro-7.beta.-methyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane")
Compound 14A 9.alpha.-tert-Butyl-1.alpha.,2.beta.,6.beta.-trihydro-7.alpha.,9.beta.-dimethyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane
![9.alpha.-tert-Butyl-1.alpha.,2.beta.,6.beta.-trihydro-7.alpha.,9.beta.-dimethyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane](/api/compound/71FXeDBlCzh.png?h=300&w=458 "9.alpha.-tert-Butyl-1.alpha.,2.beta.,6.beta.-trihydro-7.alpha.,9.beta.-dimethyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane")
Compound 14B 9.alpha.-tert-Butyl-1.alpha.,2.beta.,6.beta.,9.beta.-tetrahydro-7.alpha.-methyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane
![9.alpha.-tert-Butyl-1.alpha.,2.beta.,6.beta.,9.beta.-tetrahydro-7.alpha.-methyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane](/api/compound/5ICkZb63RAJ.png?h=300&w=458 "9.alpha.-tert-Butyl-1.alpha.,2.beta.,6.beta.,9.beta.-tetrahydro-7.alpha.-methyl-8,10-dioxa-11-oxotricyclo[6.4.0.0(2,6)]undecane")
Compound 15 9-ALPHA-TERT.-BUTYL-1-BETA,2-BETA,6-BETA,9-BETA-TETRAHYDRO-7-BETA-METHYL-8,10-DIOXA-11-OXOTRICYCLO-[6.4.0.0(2,6)]-UNDECANE
![9-ALPHA-TERT.-BUTYL-1-BETA,2-BETA,6-BETA,9-BETA-TETRAHYDRO-7-BETA-METHYL-8,10-DIOXA-11-OXOTRICYCLO-[6.4.0.0(2,6)]-UNDECANE](/api/compound/8BPVuZ96Jza.png?h=300&w=458 "9-ALPHA-TERT.-BUTYL-1-BETA,2-BETA,6-BETA,9-BETA-TETRAHYDRO-7-BETA-METHYL-8,10-DIOXA-11-OXOTRICYCLO-[6.4.0.0(2,6)]-UNDECANE")
Compound 24 METHYL-5-HYDROXY-5,6,6-TRIMETHYL-3-OXOHEPTANOATE
Compound 25 6-TERT.-BUTYL-5,6-DIHYDRO-6-METHYL-2H-PYRAN-2,4-DIONE
Compound 26 6-TERT.-BUTYL-5,6-DIHYDRO-4-METHOXY-6-METHYL-2H-PYRAN-2-ONE
Compound 27 4-BETA-N-BUTYL-6-ALPHA-TERT.-BUTYL-TETRAHYDRO-4-ALPHA,6-BETA-DIMETHYL-2H-PYRAN-2-ONE
Compound 29 2-TERT.-BUTYL-2,3-DIHYDRO-6-METHYL-4H-PYRAN-4-ONE
Compound 31 2-BETA-N-BUTYL-6-ALPHA-TERT.-BUTYL-TETRAHYDRO-2-ALPHA-METHYL-4H-PYRAN-4-ONE
Citation
| Citation | J.AM.CHEM.SOC.,116,3312(1994) |
|---|---|
| Journal | Journal of the American Chemical Society |
| Issue | 8 |
| Volume | 116 |
| Page(s) | 3312-3323 |
| Year | 1994 |
| Author(s) | Michael G. Organ, Robert D. J. Froese, John D. Goddard, Nicholas J. Taylor, Gordon L. Lange |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ja00087a018 |