(2S)-[2-(TERT.-BUTYLDIMETHYLSILANOXY)-ETHYL]-(3S)-ISOPROPYL-(1R)-[(2R)-METHOXY-(2R)-PHENYL-3,3,3-TRIFLUOROPROPIONATO]-(2S)-METHYLCYCLOPENTANE
Compound with spectra: 1 NMR
![(2S)-[2-(TERT.-BUTYLDIMETHYLSILANOXY)-ETHYL]-(3S)-ISOPROPYL-(1R)-[(2R)-METHOXY-(2R)-PHENYL-3,3,3-TRIFLUOROPROPIONATO]-(2S)-METHYLCYCLOPENTANE](/api/compound/1pZrKHDHsax.png?ph=true&h=300&w=458 "(2S)-[2-(TERT.-BUTYLDIMETHYLSILANOXY)-ETHYL]-(3S)-ISOPROPYL-(1R)-[(2R)-METHOXY-(2R)-PHENYL-3,3,3-TRIFLUOROPROPIONATO]-(2S)-METHYLCYCLOPENTANE")
| SpectraBase Compound ID | 1pZrKHDHsax |
|---|---|
| InChI | InChI=1S/C27H43F3O4Si/c1-19(2)21-15-16-22(25(21,6)17-18-33-35(8,9)24(3,4)5)34-23(31)26(32-7,27(28,29)30)20-13-11-10-12-14-20/h10-14,19,21-22H,15-18H2,1-9H3/t21-,22+,25?,26+/m0/s1 |
| InChIKey | PINGAXDGBDSZBV-HJUZIOEJSA-N |
| Mol Weight | 516.7 g/mol |
| Molecular Formula | C27H43F3O4Si |
| Exact Mass | 516.288271 g/mol |
| Enantiomer InChIKey | PINGAXDGBDSZBV-MBYQBZCVSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
MADOLIN_W-(S)-MTPA-ESTER
(1S2S,5S,6R)-5-[3,3,3-Trifluoro-2-((S)-methoxy)-2-phenyl-propionyloxy]-bicyclo[4.2.0]octane-2-carboxylic acid methyl ester
(+)-5-Hydroxy-2-methyl-6-(diethoxymethyl)-1-cyclohexenecarbaldehyde (R)-MTPA ester
[2,2-Dimethyl-7-formyl-3,4-dihydro-2H-benzo[b][1,4]dioxepin-3-yl.alpha.-Methoxy-.alpha.-(trifluoro)methylphenylacetic acid ester ] (S,S)-MTPA ester
(S,R)-MTPA ester [.alpha.-Methoxy-.alpha.-(trifluoro)methylphenylacetic acid 2,2-dimethyl-7-formyl-3,4-dihydro-2H-benzo[b][1,4]dioxepin-3-yl.alpha.-Methoxy-.alpha.-(trifluoro)methylphenylacetic acid ester]
(1S,2R,3S,4R)-3-Hydroxymethyl-2-triphenylstannylbicyclo[2.2.1]heptane (S)-Mosher's ester
(1R,6R,9R)-9-[ (R)-.alpha.-Methoxy-.alpha.-trifluoromethylphenylacetoxy]-7-oxabicyclo[4.3.0]non-4-en-8-one
(1R,6R,9R)-9-[ (S)-.alpha.-Methoxy-.alpha.-trifluoromethylphenylacetoxy]-7-oxabicyclo[4.3.0]non-4-en-8-one
DOZIWHUNXWLTNY-ALFRMZMSSA-N
(3R,4S)-1-(Trimethylsilyl)-4-[(N-benzoyl-N-[(trimethylsilyl)methyl]amino]-1(E)-penten-3-ol (S)-methoxy(trifluoromethyl)phenylacetic acid ester
| Title | Journal or Book | Year |
|---|---|---|
| Total Synthesis of (+)-4,5-Deoxyneodolabelline | Journal of the American Chemical Society | 2003 |